Hetero-binuclear near-infrared (NIR) luminescent ZnLn (Ln = Nd, Yb or Er) complexes self-assembled from the benzimidazole-based ligand

Guo Xiang Shi; Wei Xu Feng; Dan Zou; Xing Qiang Lü; Zhao Zhang; Yao Zhang; Dai Di Fan; Shun Sheng Zhao; Rick W K WONG; Richard A. Jones

doi:10.1016/j.inoche.2012.05.041

Hetero-binuclear near-infrared (NIR) luminescent ZnLn (Ln = Nd, Yb or Er) complexes self-assembled from the benzimidazole-based ligand

Guo Xiang Shi
, Wei Xu Feng
, Dan Zou
, Xing Qiang Lü^*
, Zhao Zhang
, Yao Zhang
, Dai Di Fan
, Shun Sheng Zhao
, Rick W K WONG
, Richard A. Jones

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

6 Citations (Scopus)

Abstract

With the [Zn(HL) ₂(Py)] compound from the benzimidazole-based ligand H ₂L (H ₂L: 2-(1H-benzo[d]imidazol-2-yl)-6- methoxyohenol) as the precursor, the series of four hetero-binuclear ZnLn arrayed complexes [ZnLn(HL) ₂(Py)(NO ₃) ₃] (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) have been obtained by the further reaction with Ln(NO ₃) ₃·6H ₂O, respectively. The result of their photophysical properties shows that the strong and characteristic NIR luminescence of Nd ^{3 +} or Yb ^{3 +} ion with emissive lifetimes in microsecond range, has been sensitized from the excited state ( ¹LC and ³LC) of the benzimidazole-based ligand.

Original language	English
Pages (from-to)	126-130
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	22
DOIs	https://doi.org/10.1016/j.inoche.2012.05.041
Publication status	Published - Aug 2012

User-Defined Keywords

NIR luminescence
Sensitization and energy transfer
ZnLn arrayed benzimidazole-based complexes

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10.1016/j.inoche.2012.05.041

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@article{85b00949ac15410384a1818284df0565,

title = "Hetero-binuclear near-infrared (NIR) luminescent ZnLn (Ln = Nd, Yb or Er) complexes self-assembled from the benzimidazole-based ligand",

abstract = "With the [Zn(HL) 2(Py)] compound from the benzimidazole-based ligand H 2L (H 2L: 2-(1H-benzo[d]imidazol-2-yl)-6- methoxyohenol) as the precursor, the series of four hetero-binuclear ZnLn arrayed complexes [ZnLn(HL) 2(Py)(NO 3) 3] (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) have been obtained by the further reaction with Ln(NO 3) 3·6H 2O, respectively. The result of their photophysical properties shows that the strong and characteristic NIR luminescence of Nd 3 + or Yb 3 + ion with emissive lifetimes in microsecond range, has been sensitized from the excited state ( 1LC and 3LC) of the benzimidazole-based ligand.",

keywords = "NIR luminescence, Sensitization and energy transfer, ZnLn arrayed benzimidazole-based complexes",

author = "Shi, \{Guo Xiang\} and Feng, \{Wei Xu\} and Dan Zou and L{\"u}, \{Xing Qiang\} and Zhao Zhang and Yao Zhang and Fan, \{Dai Di\} and Zhao, \{Shun Sheng\} and WONG, \{Rick W K\} and Jones, \{Richard A.\}",

note = "Funding Information: This work is funded by the National Natural Science Foundation ( 21173165 , 20871098 ), the Program for New Century Excellent Talents in University from the Ministry of Education of China ( NCET-10-0936 ), the research fund for the Doctoral Program ( 20116101110003 ) of Higher Education of China , the State Key Laboratory of Structure Chemistry ( 20100014 ), the Provincial Natural Foundation ( 2011JQ2011 ) of Shaanxi, the Education Committee Foundation of Shaanxi Province ( 11JK0588 ), Hong Kong Research Grants Council ( HKBU 202407 and FRG/06-07/II-16 ) in P. R. of China, the Robert A. Welch Foundation (Grant F-816 ), the Texas Higher Education Coordinating Board ( ARP 003658-0010-2006 ) and the Petroleum Research Fund , administered by the American Chemical Society ( 47014-AC5 ). ",

year = "2012",

month = aug,

doi = "10.1016/j.inoche.2012.05.041",

language = "English",

volume = "22",

pages = "126--130",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Hetero-binuclear near-infrared (NIR) luminescent ZnLn (Ln = Nd, Yb or Er) complexes self-assembled from the benzimidazole-based ligand

AU - Shi, Guo Xiang

AU - Feng, Wei Xu

AU - Zou, Dan

AU - Lü, Xing Qiang

AU - Zhang, Zhao

AU - Zhang, Yao

AU - Fan, Dai Di

AU - Zhao, Shun Sheng

AU - WONG, Rick W K

AU - Jones, Richard A.

N1 - Funding Information: This work is funded by the National Natural Science Foundation ( 21173165 , 20871098 ), the Program for New Century Excellent Talents in University from the Ministry of Education of China ( NCET-10-0936 ), the research fund for the Doctoral Program ( 20116101110003 ) of Higher Education of China , the State Key Laboratory of Structure Chemistry ( 20100014 ), the Provincial Natural Foundation ( 2011JQ2011 ) of Shaanxi, the Education Committee Foundation of Shaanxi Province ( 11JK0588 ), Hong Kong Research Grants Council ( HKBU 202407 and FRG/06-07/II-16 ) in P. R. of China, the Robert A. Welch Foundation (Grant F-816 ), the Texas Higher Education Coordinating Board ( ARP 003658-0010-2006 ) and the Petroleum Research Fund , administered by the American Chemical Society ( 47014-AC5 ).

PY - 2012/8

Y1 - 2012/8

N2 - With the [Zn(HL) 2(Py)] compound from the benzimidazole-based ligand H 2L (H 2L: 2-(1H-benzo[d]imidazol-2-yl)-6- methoxyohenol) as the precursor, the series of four hetero-binuclear ZnLn arrayed complexes [ZnLn(HL) 2(Py)(NO 3) 3] (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) have been obtained by the further reaction with Ln(NO 3) 3·6H 2O, respectively. The result of their photophysical properties shows that the strong and characteristic NIR luminescence of Nd 3 + or Yb 3 + ion with emissive lifetimes in microsecond range, has been sensitized from the excited state ( 1LC and 3LC) of the benzimidazole-based ligand.

AB - With the [Zn(HL) 2(Py)] compound from the benzimidazole-based ligand H 2L (H 2L: 2-(1H-benzo[d]imidazol-2-yl)-6- methoxyohenol) as the precursor, the series of four hetero-binuclear ZnLn arrayed complexes [ZnLn(HL) 2(Py)(NO 3) 3] (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) have been obtained by the further reaction with Ln(NO 3) 3·6H 2O, respectively. The result of their photophysical properties shows that the strong and characteristic NIR luminescence of Nd 3 + or Yb 3 + ion with emissive lifetimes in microsecond range, has been sensitized from the excited state ( 1LC and 3LC) of the benzimidazole-based ligand.

KW - NIR luminescence

KW - Sensitization and energy transfer

KW - ZnLn arrayed benzimidazole-based complexes

UR - https://www.scopus.com/pages/publications/84863332438

U2 - 10.1016/j.inoche.2012.05.041

DO - 10.1016/j.inoche.2012.05.041

M3 - Journal article

AN - SCOPUS:84863332438

SN - 1387-7003

VL - 22

SP - 126

EP - 130

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Hetero-binuclear near-infrared (NIR) luminescent ZnLn (Ln = Nd, Yb or Er) complexes self-assembled from the benzimidazole-based ligand

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