Graphite as a highly efficient and stable catalyst for the production of lactones

Yue Fang Li; Ming Qi Guo; Shuang Feng Yin; Lang Chen; Yong Bo Zhou; Ren Hua Qiu; Chak Tong AU

doi:10.1016/j.carbon.2012.12.036

Graphite as a highly efficient and stable catalyst for the production of lactones

Yue Fang Li, Ming Qi Guo, Shuang Feng Yin^*, Lang Chen, Yong Bo Zhou, Ren Hua Qiu, Chak Tong AU

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

The carbon materials carbon nanotubes (CNTs), graphite, and activated carbon were tested as metal-free catalysts. They showed excellent activity and selectivity in the Baeyer-Villiger (B-V) oxidation of cyclohexanone at room temperature using dioxygen (O₂) as oxidant and benzaldehyde as sacrificial agent. Among them graphite was found to be the most suitable for the formation of lactones from cyclic ketones, showing good recyclability and reusability. The use of the metal-free catalysts enables a green process for the production of lactones from ketones under mild reactions.

Original language	English
Pages (from-to)	269-275
Number of pages	7
Journal	Carbon
Volume	55
DOIs	https://doi.org/10.1016/j.carbon.2012.12.036
Publication status	Published - Apr 2013

Scopus Subject Areas

Chemistry(all)
Materials Science(all)

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10.1016/j.carbon.2012.12.036

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title = "Graphite as a highly efficient and stable catalyst for the production of lactones",

abstract = "The carbon materials carbon nanotubes (CNTs), graphite, and activated carbon were tested as metal-free catalysts. They showed excellent activity and selectivity in the Baeyer-Villiger (B-V) oxidation of cyclohexanone at room temperature using dioxygen (O2) as oxidant and benzaldehyde as sacrificial agent. Among them graphite was found to be the most suitable for the formation of lactones from cyclic ketones, showing good recyclability and reusability. The use of the metal-free catalysts enables a green process for the production of lactones from ketones under mild reactions.",

author = "Li, {Yue Fang} and Guo, {Ming Qi} and Yin, {Shuang Feng} and Lang Chen and Zhou, {Yong Bo} and Qiu, {Ren Hua} and AU, {Chak Tong}",

note = "Funding Information: The project was financially supported by the program for New Century Excellent Talents in Universities (Grant No. NCET-10-0371 ), the National Natural Science Foundation of China (Grant No. U1162109 ), Hunan Provincial Natural Science Foundation of China (Grant No. 10JJ1003 ), and the Fundamental Research Funds for the Central Universities . C.T. Au thanks the Hunan University for an adjunct professorship. ",

year = "2013",

month = apr,

doi = "10.1016/j.carbon.2012.12.036",

language = "English",

volume = "55",

pages = "269--275",

journal = "Carbon",

issn = "0008-6223",

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T1 - Graphite as a highly efficient and stable catalyst for the production of lactones

AU - Li, Yue Fang

AU - Guo, Ming Qi

AU - Yin, Shuang Feng

AU - Chen, Lang

AU - Zhou, Yong Bo

AU - Qiu, Ren Hua

AU - AU, Chak Tong

N1 - Funding Information: The project was financially supported by the program for New Century Excellent Talents in Universities (Grant No. NCET-10-0371 ), the National Natural Science Foundation of China (Grant No. U1162109 ), Hunan Provincial Natural Science Foundation of China (Grant No. 10JJ1003 ), and the Fundamental Research Funds for the Central Universities . C.T. Au thanks the Hunan University for an adjunct professorship.

PY - 2013/4

Y1 - 2013/4

N2 - The carbon materials carbon nanotubes (CNTs), graphite, and activated carbon were tested as metal-free catalysts. They showed excellent activity and selectivity in the Baeyer-Villiger (B-V) oxidation of cyclohexanone at room temperature using dioxygen (O2) as oxidant and benzaldehyde as sacrificial agent. Among them graphite was found to be the most suitable for the formation of lactones from cyclic ketones, showing good recyclability and reusability. The use of the metal-free catalysts enables a green process for the production of lactones from ketones under mild reactions.

AB - The carbon materials carbon nanotubes (CNTs), graphite, and activated carbon were tested as metal-free catalysts. They showed excellent activity and selectivity in the Baeyer-Villiger (B-V) oxidation of cyclohexanone at room temperature using dioxygen (O2) as oxidant and benzaldehyde as sacrificial agent. Among them graphite was found to be the most suitable for the formation of lactones from cyclic ketones, showing good recyclability and reusability. The use of the metal-free catalysts enables a green process for the production of lactones from ketones under mild reactions.

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U2 - 10.1016/j.carbon.2012.12.036

DO - 10.1016/j.carbon.2012.12.036

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VL - 55

SP - 269

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JO - Carbon

JF - Carbon

SN - 0008-6223

ER -

Graphite as a highly efficient and stable catalyst for the production of lactones

Abstract

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