Graphene oxide-SiO2 nanocomposite as the adsorbent for extraction and preconcentration of plant hormones for HPLC analysis

Xiaona Zhang; Jiahua Niu; Xiaoting Zhang; Rui Xiao; Minghua Lu; Zongwei Cai

doi:10.1016/j.jchromb.2017.01.004

Graphene oxide-SiO₂ nanocomposite as the adsorbent for extraction and preconcentration of plant hormones for HPLC analysis

Xiaona Zhang, Jiahua Niu, Xiaoting Zhang, Rui Xiao, Minghua Lu^*, Zongwei Cai

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

68 Citations (Scopus)

Abstract

In this research, a modified Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method based on graphene oxide@SiO₂(SiO₂@GO) nanocomposite as adsorbent of dispersive solid-phase extraction (dSPE) combined with high performance liquid chromatography (HPLC) for the analysis of four plant hormones in different plants was established. The as-prepared SiO₂@GO was characterized by scanning electron microscopy, transmission electron microscopy and infrared spectroscopy. The experimental conditions for dSPE, including the ratio of material to liquid, pH of sample, adsorption and desorption time, desorption temperature as well as desorption solution, were investigated. The detection limits for the analysis of indole-3-acetic acid, indole-3-butyric acid, 1-naphthylacetic acid and abscisic acid were achieved below 0.05 μg mL⁻¹. The established method was applied to the analysis of the plant hormones in fruits, vegetables and other food samples. The obtained results indicated that the method was sensitive, accurate, convenient and quick, which provided an alternative analytical approach for plant hormones in complex matrices.

Original language	English
Pages (from-to)	58-64
Number of pages	7
Journal	Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences
Volume	1046
DOIs	https://doi.org/10.1016/j.jchromb.2017.01.004
Publication status	Published - 1 Mar 2017

Scopus Subject Areas

Analytical Chemistry
Biochemistry
Clinical Biochemistry
Cell Biology

User-Defined Keywords

Dispersive solid-phase extraction
Graphene oxide-SiO nanocomposite
HPLC
Plant hormones
QuEChERS

Access to Document

10.1016/j.jchromb.2017.01.004

Cite this

@article{69094ab6af9148e6833cea103a86fcce,

title = "Graphene oxide-SiO2 nanocomposite as the adsorbent for extraction and preconcentration of plant hormones for HPLC analysis",

abstract = "In this research, a modified Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method based on graphene oxide@SiO2(SiO2@GO) nanocomposite as adsorbent of dispersive solid-phase extraction (dSPE) combined with high performance liquid chromatography (HPLC) for the analysis of four plant hormones in different plants was established. The as-prepared SiO2@GO was characterized by scanning electron microscopy, transmission electron microscopy and infrared spectroscopy. The experimental conditions for dSPE, including the ratio of material to liquid, pH of sample, adsorption and desorption time, desorption temperature as well as desorption solution, were investigated. The detection limits for the analysis of indole-3-acetic acid, indole-3-butyric acid, 1-naphthylacetic acid and abscisic acid were achieved below 0.05 μg mL−1. The established method was applied to the analysis of the plant hormones in fruits, vegetables and other food samples. The obtained results indicated that the method was sensitive, accurate, convenient and quick, which provided an alternative analytical approach for plant hormones in complex matrices.",

keywords = "Dispersive solid-phase extraction, Graphene oxide-SiO nanocomposite, HPLC, Plant hormones, QuEChERS",

author = "Xiaona Zhang and Jiahua Niu and Xiaoting Zhang and Rui Xiao and Minghua Lu and Zongwei Cai",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = mar,

day = "1",

doi = "10.1016/j.jchromb.2017.01.004",

language = "English",

volume = "1046",

pages = "58--64",

journal = "Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences",

issn = "1570-0232",

publisher = "Elsevier",

}

Graphene oxide-SiO₂ nanocomposite as the adsorbent for extraction and preconcentration of plant hormones for HPLC analysis. / Zhang, Xiaona; Niu, Jiahua; Zhang, Xiaoting et al.
In: Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences, Vol. 1046, 01.03.2017, p. 58-64.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Graphene oxide-SiO2 nanocomposite as the adsorbent for extraction and preconcentration of plant hormones for HPLC analysis

AU - Zhang, Xiaona

AU - Niu, Jiahua

AU - Zhang, Xiaoting

AU - Xiao, Rui

AU - Lu, Minghua

AU - Cai, Zongwei

PY - 2017/3/1

Y1 - 2017/3/1

N2 - In this research, a modified Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method based on graphene oxide@SiO2(SiO2@GO) nanocomposite as adsorbent of dispersive solid-phase extraction (dSPE) combined with high performance liquid chromatography (HPLC) for the analysis of four plant hormones in different plants was established. The as-prepared SiO2@GO was characterized by scanning electron microscopy, transmission electron microscopy and infrared spectroscopy. The experimental conditions for dSPE, including the ratio of material to liquid, pH of sample, adsorption and desorption time, desorption temperature as well as desorption solution, were investigated. The detection limits for the analysis of indole-3-acetic acid, indole-3-butyric acid, 1-naphthylacetic acid and abscisic acid were achieved below 0.05 μg mL−1. The established method was applied to the analysis of the plant hormones in fruits, vegetables and other food samples. The obtained results indicated that the method was sensitive, accurate, convenient and quick, which provided an alternative analytical approach for plant hormones in complex matrices.

AB - In this research, a modified Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method based on graphene oxide@SiO2(SiO2@GO) nanocomposite as adsorbent of dispersive solid-phase extraction (dSPE) combined with high performance liquid chromatography (HPLC) for the analysis of four plant hormones in different plants was established. The as-prepared SiO2@GO was characterized by scanning electron microscopy, transmission electron microscopy and infrared spectroscopy. The experimental conditions for dSPE, including the ratio of material to liquid, pH of sample, adsorption and desorption time, desorption temperature as well as desorption solution, were investigated. The detection limits for the analysis of indole-3-acetic acid, indole-3-butyric acid, 1-naphthylacetic acid and abscisic acid were achieved below 0.05 μg mL−1. The established method was applied to the analysis of the plant hormones in fruits, vegetables and other food samples. The obtained results indicated that the method was sensitive, accurate, convenient and quick, which provided an alternative analytical approach for plant hormones in complex matrices.

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