Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand

Huatian Shi, Jianhui Xie, William W.Y. Lam, Wai Lun MAN, Chi Keung Mak, Shek Man Yiu, Hung Kay Lee, Tai Chu Lau*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV(TAML)(N-Mes)] (1), are reported. Compound 1 is oxidized by [(p-BrC6H4)3N]+.[SbCl6] and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions.

Original languageEnglish
Pages (from-to)12895-12899
Number of pages5
JournalChemistry - A European Journal
Volume25
Issue number56
DOIs
Publication statusPublished - 8 Oct 2019

Scopus Subject Areas

  • Catalysis
  • Organic Chemistry

User-Defined Keywords

  • coordination chemistry
  • hydrogen atom transfer
  • imido transfer
  • manganese
  • one-electron oxidation

Fingerprint

Dive into the research topics of 'Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand'. Together they form a unique fingerprint.

Cite this