@article{033a91733f4b440e9cf73702547e24f4,
title = "Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand",
abstract = "The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV(TAML)(N-Mes)]− (1), are reported. Compound 1 is oxidized by [(p-BrC6H4)3N]+.[SbCl6]− and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions.",
keywords = "coordination chemistry, hydrogen atom transfer, imido transfer, manganese, one-electron oxidation",
author = "Huatian Shi and Jianhui Xie and Lam, {William W.Y.} and Man, {Wai Lun} and Mak, {Chi Keung} and Yiu, {Shek Man} and Lee, {Hung Kay} and Lau, {Tai Chu}",
note = "Funding Information: This research is supported by the Research Grants Council of Hong Kong (CityU 11302917), the Hong Kong University Grants Committee (AoE/P-03-08) and the National Natural Science Foundation of China (21801058). We thank Dr. C. Y. Wong and Dr. K. C. Lau for helpful discussions.",
year = "2019",
month = oct,
day = "8",
doi = "10.1002/chem.201902405",
language = "English",
volume = "25",
pages = "12895--12899",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "56",
}