Gas-cycle-assisted headspace solid-phase microextraction coupled with gas chromatography for rapid analysis of organic pollutants

Wenli Zhu; Peige Qin; Lizhen Han; Xiaowan Zhang; Dan Li; Mengyuan Li; Youmei Wang; Xuebin Zhang; Minghua Lu; Zongwei Cai

doi:10.1039/d1cc02771a

Gas-cycle-assisted headspace solid-phase microextraction coupled with gas chromatography for rapid analysis of organic pollutants

Wenli Zhu, Peige Qin, Lizhen Han, Xiaowan Zhang, Dan Li, Mengyuan Li, Youmei Wang, Xuebin Zhang, Minghua Lu^*, Zongwei Cai^*

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › peer-review

22 Citations (Scopus)

Abstract

Herein, a new gas-cycle-assisted (GCA) headspace solid-phase microextraction (HS-SPME) device was designed to rapidly extract organic pollutants with highK_owand boiling points, which have difficulty in volatilization from matrix to headspace. Organic pollutants, including three polycyclic aromatic hydrocarbons (PAHs), four polychlorinated biphenyls (PCBs), and five phthalate esters (PAEs), were selected to evaluate the performance of GCA HS-SPME. Compared with conventional HS-SPME, the equilibrium times of GCA HS-SPME for extraction of PAHs, PCBs, and PAEs were greatly shortened from 70-90 to 5-11 min. Moreover, the limits of detection for analysis of PAHs were achieved at pg mL⁻¹level by GCA HS-SPME coupled with gas chromatography-flame ionization detection.

Original language	English
Pages (from-to)	8810-8813
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	70
Early online date	6 Aug 2021
DOIs	https://doi.org/10.1039/d1cc02771a
Publication status	Published - 11 Sept 2021

Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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@article{00365706bc474c268394c687dad3f3d3,

title = "Gas-cycle-assisted headspace solid-phase microextraction coupled with gas chromatography for rapid analysis of organic pollutants",

abstract = "Herein, a new gas-cycle-assisted (GCA) headspace solid-phase microextraction (HS-SPME) device was designed to rapidly extract organic pollutants with highKowand boiling points, which have difficulty in volatilization from matrix to headspace. Organic pollutants, including three polycyclic aromatic hydrocarbons (PAHs), four polychlorinated biphenyls (PCBs), and five phthalate esters (PAEs), were selected to evaluate the performance of GCA HS-SPME. Compared with conventional HS-SPME, the equilibrium times of GCA HS-SPME for extraction of PAHs, PCBs, and PAEs were greatly shortened from 70-90 to 5-11 min. Moreover, the limits of detection for analysis of PAHs were achieved at pg mL−1level by GCA HS-SPME coupled with gas chromatography-flame ionization detection.",

author = "Wenli Zhu and Peige Qin and Lizhen Han and Xiaowan Zhang and Dan Li and Mengyuan Li and Youmei Wang and Xuebin Zhang and Minghua Lu and Zongwei Cai",

note = "This work was sponsored by the National Nature Science Foundation of China (22076038), and Natural Science Foundation of Henan Province (202300410044). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = sep,

day = "11",

doi = "10.1039/d1cc02771a",

language = "English",

volume = "57",

pages = "8810--8813",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "70",

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TY - JOUR

T1 - Gas-cycle-assisted headspace solid-phase microextraction coupled with gas chromatography for rapid analysis of organic pollutants

AU - Zhu, Wenli

AU - Qin, Peige

AU - Han, Lizhen

AU - Zhang, Xiaowan

AU - Li, Dan

AU - Li, Mengyuan

AU - Wang, Youmei

AU - Zhang, Xuebin

AU - Lu, Minghua

AU - Cai, Zongwei

N1 - This work was sponsored by the National Nature Science Foundation of China (22076038), and Natural Science Foundation of Henan Province (202300410044). Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/9/11

Y1 - 2021/9/11

N2 - Herein, a new gas-cycle-assisted (GCA) headspace solid-phase microextraction (HS-SPME) device was designed to rapidly extract organic pollutants with highKowand boiling points, which have difficulty in volatilization from matrix to headspace. Organic pollutants, including three polycyclic aromatic hydrocarbons (PAHs), four polychlorinated biphenyls (PCBs), and five phthalate esters (PAEs), were selected to evaluate the performance of GCA HS-SPME. Compared with conventional HS-SPME, the equilibrium times of GCA HS-SPME for extraction of PAHs, PCBs, and PAEs were greatly shortened from 70-90 to 5-11 min. Moreover, the limits of detection for analysis of PAHs were achieved at pg mL−1level by GCA HS-SPME coupled with gas chromatography-flame ionization detection.

AB - Herein, a new gas-cycle-assisted (GCA) headspace solid-phase microextraction (HS-SPME) device was designed to rapidly extract organic pollutants with highKowand boiling points, which have difficulty in volatilization from matrix to headspace. Organic pollutants, including three polycyclic aromatic hydrocarbons (PAHs), four polychlorinated biphenyls (PCBs), and five phthalate esters (PAEs), were selected to evaluate the performance of GCA HS-SPME. Compared with conventional HS-SPME, the equilibrium times of GCA HS-SPME for extraction of PAHs, PCBs, and PAEs were greatly shortened from 70-90 to 5-11 min. Moreover, the limits of detection for analysis of PAHs were achieved at pg mL−1level by GCA HS-SPME coupled with gas chromatography-flame ionization detection.

UR - http://www.scopus.com/inward/record.url?scp=85114294037&partnerID=8YFLogxK

U2 - 10.1039/d1cc02771a

DO - 10.1039/d1cc02771a

M3 - Journal article

C2 - 34382969

AN - SCOPUS:85114294037

SN - 1359-7345

VL - 57

SP - 8810

EP - 8813

JO - Chemical Communications

JF - Chemical Communications

IS - 70

ER -

Gas-cycle-assisted headspace solid-phase microextraction coupled with gas chromatography for rapid analysis of organic pollutants

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