Formation and luminescence of 1D helical polymeric excimer from Pt-MeO-salen precursor

  • Wen Li Chai
  • , Wen Juan Jin
  • , Xing Qiang Lü*
  • , Wei Yu Bi
  • , Ji Rong Song
  • , Wai Kwok Wong*
  • , Feng Bao
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

7 Citations (Scopus)

Abstract

With the amorphous Pt-MeO-salen solid (MeO-salen = N,N′-bis(3-methoxy-salicylidene)-ethylene-1,2-diamine) as the precursor, a new 1D polymeric complex [K2(Pt-MeO-salen)2Ni(CN)4]n · 0.5nEt2O (1) has been characterized. The luminescent property of the complex shows that the 1D helical stacking of well-defined Pt-MeO-salen monomers has modulated the energy order of the excited state in solid state at different temperatures.

Original languageEnglish
Pages (from-to)699-702
Number of pages4
JournalInorganic Chemistry Communications
Volume11
Issue number6
Early online date16 Mar 2008
DOIs
Publication statusPublished - Jun 2008

User-Defined Keywords

  • Excimer
  • MeO-salen Schiff-base
  • Phosphorescence
  • Platinum(II)
  • Self-assembly

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