Through the copolymerization of a complex monomer [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2; H2L = N,N′-bis(salicylidene)cyclohexane-1.2-diamine; 4-vinyl-Py = 4-vinyl-pyridine and HTTA = 2-thenoyltrifluoroacetonate) with MMA (methyl methacrylate), the first example of PMMA-supported and highly luminous (ΦEuL = 63.1%) color-purity red-light metallopolymer poly(MMA-co-2) based on a tris-β-diketonate Zn2 +-Eu3 +-complex is obtained.
Scopus Subject Areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
- High color-purity red luminescence
- PMMA-supported metallopolymer
- Tris-β-diketonate Zn-Eu-complex