First example of PMMA-supported and highly luminous color-purity red-light metallopolymer based on a tris-β-diketonate Zn2 +-Eu3 +-complex

Yani He; Guorui Fu; Lin Liu; Hongyan Li; Baoning Li; Jiaqing Guan; Xingqiang Lü; Rick W K WONG; Richard A. Jones

doi:10.1016/j.inoche.2016.04.027

First example of PMMA-supported and highly luminous color-purity red-light metallopolymer based on a tris-β-diketonate Zn^{2 +}-Eu^{3 +}-complex

Yani He, Guorui Fu, Lin Liu, Hongyan Li, Baoning Li, Jiaqing Guan, Xingqiang Lü^*, Rick W K WONG, Richard A. Jones

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

2 Citations (Scopus)

Abstract

Through the copolymerization of a complex monomer [Zn(L)(4-vinyl-Py)Eu(TTA)₃] (2; H₂L = N,N′-bis(salicylidene)cyclohexane-1.2-diamine; 4-vinyl-Py = 4-vinyl-pyridine and HTTA = 2-thenoyltrifluoroacetonate) with MMA (methyl methacrylate), the first example of PMMA-supported and highly luminous (Φ_Eu^L = 63.1%) color-purity red-light metallopolymer poly(MMA-co-2) based on a tris-β-diketonate Zn^{2 +}-Eu^{3 +}-complex is obtained.

Original language	English
Pages (from-to)	62-65
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	69
DOIs	https://doi.org/10.1016/j.inoche.2016.04.027
Publication status	Published - 1 Jul 2016

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

High color-purity red luminescence
PMMA-supported metallopolymer
Tris-β-diketonate Zn-Eu-complex

Access to Document

10.1016/j.inoche.2016.04.027

Cite this

@article{f84db3d9bb0649548b66b06023dd3d70,

title = "First example of PMMA-supported and highly luminous color-purity red-light metallopolymer based on a tris-β-diketonate Zn2 +-Eu3 +-complex",

abstract = "Through the copolymerization of a complex monomer [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2; H2L = N,N′-bis(salicylidene)cyclohexane-1.2-diamine; 4-vinyl-Py = 4-vinyl-pyridine and HTTA = 2-thenoyltrifluoroacetonate) with MMA (methyl methacrylate), the first example of PMMA-supported and highly luminous (ΦEuL = 63.1%) color-purity red-light metallopolymer poly(MMA-co-2) based on a tris-β-diketonate Zn2 +-Eu3 +-complex is obtained.",

keywords = "High color-purity red luminescence, PMMA-supported metallopolymer, Tris-β-diketonate Zn-Eu-complex",

author = "Yani He and Guorui Fu and Lin Liu and Hongyan Li and Baoning Li and Jiaqing Guan and Xingqiang L{\"u} and WONG, {Rick W K} and Jones, {Richard A.}",

note = "Funding Information: This work is funded by the National Natural Science Foundation ( 21373160 , 91222201 , 21173165 ), the Program for New Century Excellent Talents in University from the Ministry of Education of China ( NCET-10-0936 ), the research fund for the Doctoral Program of Higher Education ( 20116101110003 ), the Science and Technology and Innovation Project (2012KTCQ01-37) and the Graduate Innovation and Creativity Fund (Visiting Learner) of Northwest University ( YZZ14046 ) in P.R. China. ",

year = "2016",

month = jul,

day = "1",

doi = "10.1016/j.inoche.2016.04.027",

language = "English",

volume = "69",

pages = "62--65",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

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TY - JOUR

T1 - First example of PMMA-supported and highly luminous color-purity red-light metallopolymer based on a tris-β-diketonate Zn2 +-Eu3 +-complex

AU - He, Yani

AU - Fu, Guorui

AU - Liu, Lin

AU - Li, Hongyan

AU - Li, Baoning

AU - Guan, Jiaqing

AU - Lü, Xingqiang

AU - WONG, Rick W K

AU - Jones, Richard A.

N1 - Funding Information: This work is funded by the National Natural Science Foundation ( 21373160 , 91222201 , 21173165 ), the Program for New Century Excellent Talents in University from the Ministry of Education of China ( NCET-10-0936 ), the research fund for the Doctoral Program of Higher Education ( 20116101110003 ), the Science and Technology and Innovation Project (2012KTCQ01-37) and the Graduate Innovation and Creativity Fund (Visiting Learner) of Northwest University ( YZZ14046 ) in P.R. China.

PY - 2016/7/1

Y1 - 2016/7/1

N2 - Through the copolymerization of a complex monomer [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2; H2L = N,N′-bis(salicylidene)cyclohexane-1.2-diamine; 4-vinyl-Py = 4-vinyl-pyridine and HTTA = 2-thenoyltrifluoroacetonate) with MMA (methyl methacrylate), the first example of PMMA-supported and highly luminous (ΦEuL = 63.1%) color-purity red-light metallopolymer poly(MMA-co-2) based on a tris-β-diketonate Zn2 +-Eu3 +-complex is obtained.

AB - Through the copolymerization of a complex monomer [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2; H2L = N,N′-bis(salicylidene)cyclohexane-1.2-diamine; 4-vinyl-Py = 4-vinyl-pyridine and HTTA = 2-thenoyltrifluoroacetonate) with MMA (methyl methacrylate), the first example of PMMA-supported and highly luminous (ΦEuL = 63.1%) color-purity red-light metallopolymer poly(MMA-co-2) based on a tris-β-diketonate Zn2 +-Eu3 +-complex is obtained.

KW - High color-purity red luminescence

KW - PMMA-supported metallopolymer

KW - Tris-β-diketonate Zn-Eu-complex

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DO - 10.1016/j.inoche.2016.04.027

M3 - Journal article

AN - SCOPUS:84965159328

SN - 1387-7003

VL - 69

SP - 62

EP - 65

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

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