First example of near-infrared (NIR) luminescent Yb4(Salen)4-containing metallopolymer through radical copolymerization with MMA (methyl methacrylate)

Lin Liu, Weixu Feng, Xingqiang Lü*, Rick W K WONG

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Through the radical copolymerization of MMA (methyl methacrylate) with a vinyl-containing complex monomer {[Yb4(L)2(HL)23-OH)2(NO3)2]·(NO3)2} (1; H2L = N,N'’-bis-(5-(3'-vinylphenyl)-3-methoxy-salicylidene)cyclohexane-1,2-diamine), the first example of PMMA-supported and Yb4(Salen)4-containing metallopolymer Poly(1-co-MMA) exhibits significantly improved physical properties besides relatively higher NIR quantum yields (ΦYbYb = 1.18% and ΦLYb = 0.86%) than those (ΦYbYb = 1.02–1.04% and ΦLYb = 0.73–0.75%) of complex monomer 1 in solution and 1@PMMA in solid state.

Original languageEnglish
Pages (from-to)29-32
Number of pages4
JournalInorganic Chemistry Communication
Volume75
DOIs
Publication statusPublished - 1 Jan 2017

Scopus Subject Areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

User-Defined Keywords

  • Metallopolymer
  • Radical copolymerization
  • Vinyl-containing Ln(Salen)-arrayed complex monomer
  • Yb-centered NIR luminescence

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