Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer

Wai Fun Yeung; Wai Lun Man; Wing Tak Wong; Tai Chu Lau; Song Gao

doi:10.1002/1521-3773(20010817)40:16<3031::aid-anie3031>3.0.co;2-%23

Ferromagnetic ordering in a diamond-like cyano-bridged Mn^IIRu^III bimetallic coordination polymer

Wai Fun Yeung^*, Wai Lun Man, Wing Tak Wong, Tai Chu Lau^*, Song Gao^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

99 Citations (Scopus)

Abstract

Cyano-mediated interaction of the alternating high-spin Mn^II centers and low-spin Ru^III centers in {Mn[Ru(acac)₂(CN)₂]₂}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel Mn^IIRu^III coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)₂(CN)₂]- and Mn²⁺ ions.

Original language	English
Pages (from-to)	3031-3033
Number of pages	3
Journal	Angewandte Chemie. International Edition
Volume	40
Issue number	16
Early online date	15 Aug 2001
DOIs	https://doi.org/10.1002/1521-3773(20010817)40:16<3031::aid-anie3031>3.0.co;2-%23
Publication status	Published - 17 Aug 2001

Scopus Subject Areas

Catalysis
General Chemistry

User-Defined Keywords

Coordination polymers
Cyanides
Magnetic properties
Manganese
Ruthenium

Access to Document

10.1002/1521-3773(20010817)40:16<3031::aid-anie3031>3.0.co;2-%23

Cite this

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title = "Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer",

abstract = "Cyano-mediated interaction of the alternating high-spin MnII centers and low-spin RuIII centers in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIII coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ ions.",

keywords = "Coordination polymers, Cyanides, Magnetic properties, Manganese, Ruthenium",

author = "Yeung, {Wai Fun} and Man, {Wai Lun} and Wong, {Wing Tak} and Lau, {Tai Chu} and Song Gao",

note = "Funding information: This work was supported by the City University of Hong Kong (7001046), the University of Hong Kong, the Research Grants Council of Hong Kong (CityU 1049/97P), the National Natural Science Foundation of China (20023005), and the National Key Project for Fundamental Research (G1998061305). Publisher copyright: {\textcopyright} 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany",

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T1 - Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer

AU - Yeung, Wai Fun

AU - Man, Wai Lun

AU - Wong, Wing Tak

AU - Lau, Tai Chu

AU - Gao, Song

N1 - Funding information: This work was supported by the City University of Hong Kong (7001046), the University of Hong Kong, the Research Grants Council of Hong Kong (CityU 1049/97P), the National Natural Science Foundation of China (20023005), and the National Key Project for Fundamental Research (G1998061305). Publisher copyright: © 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany

PY - 2001/8/17

Y1 - 2001/8/17

N2 - Cyano-mediated interaction of the alternating high-spin MnII centers and low-spin RuIII centers in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIII coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ ions.

AB - Cyano-mediated interaction of the alternating high-spin MnII centers and low-spin RuIII centers in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIII coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ ions.

KW - Coordination polymers

KW - Cyanides

KW - Magnetic properties

KW - Manganese

KW - Ruthenium

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JO - Angewandte Chemie. International Edition

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