Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer

Wai Fun Yeung*, Wai Lun Man, Wing Tak Wong, Tai Chu Lau*, Song Gao*

*Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

98 Citations (Scopus)

Abstract

Cyano-mediated interaction of the alternating high-spin MnII centers and low-spin RuIII centers in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIII coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ ions.

Original languageEnglish
Pages (from-to)3031-3033
Number of pages3
JournalAngewandte Chemie - International Edition
Volume40
Issue number16
Early online date15 Aug 2001
DOIs
Publication statusPublished - 17 Aug 2001
Externally publishedYes

Scopus Subject Areas

  • Catalysis
  • Chemistry(all)

User-Defined Keywords

  • Coordination polymers
  • Cyanides
  • Magnetic properties
  • Manganese
  • Ruthenium

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