Facile C–N bond cleavage of primary aliphatic amines by (salen)ruthenium(vi) nitrido complexes

Yunling Pan; Lin Cheng; Yi Pan; Wai Lun Man; Shek Man Yiu; Jianhui Xie; Kai Chung Lau; Tai Chu Lau

doi:10.1039/D2DT00600F

Facile C–N bond cleavage of primary aliphatic amines by (salen)ruthenium(vi) nitrido complexes

Yunling Pan
, Lin Cheng
, Yi Pan
, Wai Lun Man
, Shek Man Yiu
, Jianhui Xie^*
, Kai Chung Lau^*
, Tai Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

6 Citations (Scopus)

Abstract

We report the first example of oxidative cleavage of the strong C–N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C–N cleavage reaction comes from the formation of stable N≡N after the initial coupling of the amine N and the nitrido ligand.

Original language	English
Pages (from-to)	5404-5408
Number of pages	5
Journal	Dalton Transactions
Volume	51
Issue number	14
Early online date	14 Mar 2022
DOIs	https://doi.org/10.1039/D2DT00600F
Publication status	Published - 14 Apr 2022

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10.1039/D2DT00600F

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title = "Facile C–N bond cleavage of primary aliphatic amines by (salen)ruthenium(vi) nitrido complexes",

abstract = "We report the first example of oxidative cleavage of the strong C–N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C–N cleavage reaction comes from the formation of stable N≡N after the initial coupling of the amine N and the nitrido ligand.",

author = "Yunling Pan and Lin Cheng and Yi Pan and Man, \{Wai Lun\} and Yiu, \{Shek Man\} and Jianhui Xie and Lau, \{Kai Chung\} and Lau, \{Tai Chu\}",

note = "Funding Information: The work was supported by the National Natural Science Foundation of China (21801058), the Fundamental Research Funds for the Central Universities (JZ2021HGTB0118 and PA2021KCPY0057), City University of Hong Kong (7005253), the Hong Kong Research Grants Council (CityU 11336816), and the NSFC/RGC Joint Research Scheme (N\_CityU111/20). Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",

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doi = "10.1039/D2DT00600F",

language = "English",

volume = "51",

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journal = "Dalton Transactions",

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TY - JOUR

T1 - Facile C–N bond cleavage of primary aliphatic amines by (salen)ruthenium(vi) nitrido complexes

AU - Pan, Yunling

AU - Cheng, Lin

AU - Pan, Yi

AU - Man, Wai Lun

AU - Yiu, Shek Man

AU - Xie, Jianhui

AU - Lau, Kai Chung

AU - Lau, Tai Chu

N1 - Funding Information: The work was supported by the National Natural Science Foundation of China (21801058), the Fundamental Research Funds for the Central Universities (JZ2021HGTB0118 and PA2021KCPY0057), City University of Hong Kong (7005253), the Hong Kong Research Grants Council (CityU 11336816), and the NSFC/RGC Joint Research Scheme (N_CityU111/20). Publisher Copyright: © 2022 The Royal Society of Chemistry

PY - 2022/4/14

Y1 - 2022/4/14

N2 - We report the first example of oxidative cleavage of the strong C–N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C–N cleavage reaction comes from the formation of stable N≡N after the initial coupling of the amine N and the nitrido ligand.

AB - We report the first example of oxidative cleavage of the strong C–N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C–N cleavage reaction comes from the formation of stable N≡N after the initial coupling of the amine N and the nitrido ligand.

UR - https://www.scopus.com/pages/publications/85127696907

U2 - 10.1039/D2DT00600F

DO - 10.1039/D2DT00600F

M3 - Journal article

SN - 1477-9226

VL - 51

SP - 5404

EP - 5408

JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

Facile C–N bond cleavage of primary aliphatic amines by (salen)ruthenium(vi) nitrido complexes

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