Experimental assessment of the efficacy of sensitised emission in water from a europium ion, following intramolecular excitation by a phenanthridinyl group

Ian M. Clarkson; Andrew Beeby; James I. Bruce; Linda J. Govenlock; Mark P. Lowe; Céline E. Mathieu; David Parker; Kanthi Senanayake

doi:10.1039/b001319f

Experimental assessment of the efficacy of sensitised emission in water from a europium ion, following intramolecular excitation by a phenanthridinyl group

Ian M. Clarkson
, Andrew Beeby
, James I. Bruce
, Linda J. Govenlock
, Mark P. Lowe
, Céline E. Mathieu
, David Parker^*
, Kanthi Senanayake

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

52 Citations (Scopus)

Abstract

The overall quantum yields for phenanthridinium sensitised emission from a europium ion have been measured in H₂O and D₂O for a series of five structurally related, octadentate ligands in which the distance from the phenanthridinium chromophore to the Eu ion varies from 2.5 to ca. 8.2 Å. Overall quantum yields (pD ≤ 2) range from 0.25 to 0.012 suggesting that the experimental distance for 50% efficiency of intramolecular energy transfer lies close to 5.5 Å for this system.

Original language	English
Pages (from-to)	377-386
Number of pages	10
Journal	New Journal of Chemistry
Volume	24
Issue number	6
DOIs	https://doi.org/10.1039/b001319f
Publication status	Published - 23 May 2000

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title = "Experimental assessment of the efficacy of sensitised emission in water from a europium ion, following intramolecular excitation by a phenanthridinyl group",

abstract = "The overall quantum yields for phenanthridinium sensitised emission from a europium ion have been measured in H2O and D2O for a series of five structurally related, octadentate ligands in which the distance from the phenanthridinium chromophore to the Eu ion varies from 2.5 to ca. 8.2 {\AA}. Overall quantum yields (pD ≤ 2) range from 0.25 to 0.012 suggesting that the experimental distance for 50\% efficiency of intramolecular energy transfer lies close to 5.5 {\AA} for this system.",

author = "Clarkson, \{Ian M.\} and Andrew Beeby and Bruce, \{James I.\} and Govenlock, \{Linda J.\} and Lowe, \{Mark P.\} and Mathieu, \{C{\'e}line E.\} and David Parker and Kanthi Senanayake",

year = "2000",

month = may,

day = "23",

doi = "10.1039/b001319f",

language = "English",

volume = "24",

pages = "377--386",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Experimental assessment of the efficacy of sensitised emission in water from a europium ion, following intramolecular excitation by a phenanthridinyl group

AU - Clarkson, Ian M.

AU - Beeby, Andrew

AU - Bruce, James I.

AU - Govenlock, Linda J.

AU - Lowe, Mark P.

AU - Mathieu, Céline E.

AU - Parker, David

AU - Senanayake, Kanthi

PY - 2000/5/23

Y1 - 2000/5/23

N2 - The overall quantum yields for phenanthridinium sensitised emission from a europium ion have been measured in H2O and D2O for a series of five structurally related, octadentate ligands in which the distance from the phenanthridinium chromophore to the Eu ion varies from 2.5 to ca. 8.2 Å. Overall quantum yields (pD ≤ 2) range from 0.25 to 0.012 suggesting that the experimental distance for 50% efficiency of intramolecular energy transfer lies close to 5.5 Å for this system.

AB - The overall quantum yields for phenanthridinium sensitised emission from a europium ion have been measured in H2O and D2O for a series of five structurally related, octadentate ligands in which the distance from the phenanthridinium chromophore to the Eu ion varies from 2.5 to ca. 8.2 Å. Overall quantum yields (pD ≤ 2) range from 0.25 to 0.012 suggesting that the experimental distance for 50% efficiency of intramolecular energy transfer lies close to 5.5 Å for this system.

UR - https://www.scopus.com/pages/publications/0033921613

U2 - 10.1039/b001319f

DO - 10.1039/b001319f

M3 - Journal article

AN - SCOPUS:0033921613

SN - 1144-0546

VL - 24

SP - 377

EP - 386

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 6

ER -

Experimental assessment of the efficacy of sensitised emission in water from a europium ion, following intramolecular excitation by a phenanthridinyl group

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