Enhanced Adsorption of Methyl Orange by Mongolian Montmorillonite after Aluminum Pillaring

Jiajun Chen, Jianzun Lu, Lingcheng Su*, Huada Ruan, Yijia Zhao, Chiuhong Lee, Zongwei Cai, Zhihui Wu, Yanan Jiang*

*Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

5 Citations (Scopus)

Abstract

This article studies the enhancement of methyl orange (MO) adsorption by Mongolian montmorillonite (MMt) modified by the intercalation of the Keggin Al13 complex, followed by calcination during the pillaring process. The properties of MMt, Al-intercalated MMt (P-MMt), and Al-pillared MMt (P-MMt-C) were determined using X-ray diffraction (XRD), thermogravimetric analysis (TGA), surface-area analysis, and a field emission scanning electron microscope (FE-SEM). The MO adsorption by modified MMt was subsequently evaluated. The XRD basal distance (d001) and the specific surface area (SSA) increased after the modification of MMt. The TGA results revealed that P-MMt and P-MMt-C had better thermal stability than MMt. The Al-pillared MMt obtained after calcination (e.g., P-MMt-C400) showed a larger basal distance and surface area than that without pillaring. The MO adsorption process of P-MMt-C400 was supposed to be dominated by chemisorption and heterogeneous multilayer adsorption, according to the kinetic and isotherm studies. The maximum adsorption capacity of P-MMt-C400 is 6.23 mg/g. The MO adsorption ability of Al-pillared MMt was contributed by the Keggin Al13 complex attracting MO and the increase in the surface area of macro-, meso-and micro-pores (>1.2 nm). The Al-pillared MMt in this study could be applied as an adsorbent in a water purification system to remove MO or other dye elements.

Original languageEnglish
Article number3182
JournalApplied Sciences (Switzerland)
Volume12
Issue number6
DOIs
Publication statusPublished - 21 Mar 2022

Scopus Subject Areas

  • Materials Science(all)
  • Instrumentation
  • Engineering(all)
  • Process Chemistry and Technology
  • Computer Science Applications
  • Fluid Flow and Transfer Processes

User-Defined Keywords

  • adsorption
  • Al pillaring
  • calcination
  • methyl orange
  • montmorillonite

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