Electrogenerated chemiluminescence sensor based on tris(2,2'-bipyridine)ruthenium(II)-immobilized natural clay and ionic liquid

Ping Jiang; Lei Yan; Xicui Zhang; Hongyan Yuan; Dan Xiao; Martin M F CHOI

doi:10.1002/elan.200900283

Electrogenerated chemiluminescence sensor based on tris(2,2'-bipyridine)ruthenium(II)-immobilized natural clay and ionic liquid

Ping Jiang^*, Lei Yan, Xicui Zhang, Hongyan Yuan, Dan Xiao, Martin M F CHOI

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

5 Citations (Scopus)

Abstract

A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)₃²⁺) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)₃²⁺-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)₃²⁺ was investigated. It was observed that the ECL of immobilized Ru(bpy)₃²⁺ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.

Original language	English
Pages (from-to)	204-208
Number of pages	5
Journal	Electroanalysis
Volume	22
Issue number	2
DOIs	https://doi.org/10.1002/elan.200900283
Publication status	Published - Jan 2010

Scopus Subject Areas

Analytical Chemistry
Electrochemistry

User-Defined Keywords

ECL sensor
Ionic liquids
Natural clay
Ru(bpy)
Sensors

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10.1002/elan.200900283

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@article{556561c927c143cab108736f14bc91c3,

title = "Electrogenerated chemiluminescence sensor based on tris(2,2'-bipyridine)ruthenium(II)-immobilized natural clay and ionic liquid",

abstract = "A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.",

keywords = "ECL sensor, Ionic liquids, Natural clay, Ru(bpy), Sensors",

author = "Ping Jiang and Lei Yan and Xicui Zhang and Hongyan Yuan and Dan Xiao and CHOI, {Martin M F}",

year = "2010",

month = jan,

doi = "10.1002/elan.200900283",

language = "English",

volume = "22",

pages = "204--208",

journal = "Electroanalysis",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Electrogenerated chemiluminescence sensor based on tris(2,2'-bipyridine)ruthenium(II)-immobilized natural clay and ionic liquid

AU - Jiang, Ping

AU - Yan, Lei

AU - Zhang, Xicui

AU - Yuan, Hongyan

AU - Xiao, Dan

AU - CHOI, Martin M F

PY - 2010/1

Y1 - 2010/1

N2 - A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.

AB - A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.

KW - ECL sensor

KW - Ionic liquids

KW - Natural clay

KW - Ru(bpy)

KW - Sensors

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U2 - 10.1002/elan.200900283

DO - 10.1002/elan.200900283

M3 - Journal article

AN - SCOPUS:74249099349

SN - 1040-0397

VL - 22

SP - 204

EP - 208

JO - Electroanalysis

JF - Electroanalysis

IS - 2

ER -

Electrogenerated chemiluminescence sensor based on tris(2,2'-bipyridine)ruthenium(II)-immobilized natural clay and ionic liquid

Abstract

Scopus Subject Areas

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