Electro-catalytic oxidation of methane at multi-walled carbon nanotubes-Nafion/nickel hydroxide modified nickel electrode

Jie Qiao; Shengnan Tang; Yanni Tian; Shaomin Shuang; Chuan Dong; Martin M.F. Choi

doi:10.1016/j.snb.2009.02.065

Electro-catalytic oxidation of methane at multi-walled carbon nanotubes-Nafion/nickel hydroxide modified nickel electrode

Jie Qiao
, Shengnan Tang
, Yanni Tian
, Shaomin Shuang
, Chuan Dong^*
, Martin M.F. Choi

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

31 Citations (Scopus)

Abstract

A novel chemical modified nickel (Ni) electrode based on multi-walled carbon nanotubes (MWCNTs), Nafion film and nickel hydroxide has been successfully fabricated for methane (CH₄) detection at ambient conditions. The morphology of the MWCNTs-Nafion/Ni(OH)₂ film was characterized by transmission electron microscopy and the electrochemical properties of the Ni modified electrode were studied by cyclic voltammetry. The MWCNTs-Nafion/Ni(OH)₂-Ni electrode showed good catalytic effect on the oxidation of CH₄ in 1.0 M NaOH. In addition, the modified electrode was free from nitrogen and oxygen interferences. When differential pulse voltammetry was applied to the MWCNTs-Nafion/Ni(OH)₂-Ni electrode, a good linear relationship between the oxidation peak current (i) and CH₄ concentration (C_methane) was obtained: i = 1.841C_methane + 46.25, where i is in μA and C_methane is in 0.0-16.0% (v/v). The relative standard deviation for detection of 3.0% (v/v) CH₄ was 1.80% (n = 5). The proposed Ni modified electrode is anticipated to provide a promising technique to detect CH₄ at ambient conditions.

Original language	English
Pages (from-to)	402-407
Number of pages	6
Journal	Sensors and Actuators B: Chemical
Volume	138
Issue number	2
DOIs	https://doi.org/10.1016/j.snb.2009.02.065
Publication status	Published - 6 May 2009

User-Defined Keywords

Methane
Multi-walled carbon nanotubes
Nafion
Nickel modified electrode

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10.1016/j.snb.2009.02.065

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@article{556a170d62d74cd497a8a3c3c95e8db5,

title = "Electro-catalytic oxidation of methane at multi-walled carbon nanotubes-Nafion/nickel hydroxide modified nickel electrode",

abstract = "A novel chemical modified nickel (Ni) electrode based on multi-walled carbon nanotubes (MWCNTs), Nafion film and nickel hydroxide has been successfully fabricated for methane (CH4) detection at ambient conditions. The morphology of the MWCNTs-Nafion/Ni(OH)2 film was characterized by transmission electron microscopy and the electrochemical properties of the Ni modified electrode were studied by cyclic voltammetry. The MWCNTs-Nafion/Ni(OH)2-Ni electrode showed good catalytic effect on the oxidation of CH4 in 1.0 M NaOH. In addition, the modified electrode was free from nitrogen and oxygen interferences. When differential pulse voltammetry was applied to the MWCNTs-Nafion/Ni(OH)2-Ni electrode, a good linear relationship between the oxidation peak current (i) and CH4 concentration (Cmethane) was obtained: i = 1.841Cmethane + 46.25, where i is in μA and Cmethane is in 0.0-16.0\% (v/v). The relative standard deviation for detection of 3.0\% (v/v) CH4 was 1.80\% (n = 5). The proposed Ni modified electrode is anticipated to provide a promising technique to detect CH4 at ambient conditions.",

keywords = "Methane, Multi-walled carbon nanotubes, Nafion, Nickel modified electrode",

author = "Jie Qiao and Shengnan Tang and Yanni Tian and Shaomin Shuang and Chuan Dong and Choi, \{Martin M.F.\}",

note = "Funding Information: This work is supported by the Key Project of National Natural Science Foundation of China (50534100) and the Shanxi Province Graduate Student Innovative Plan (07010700). ",

year = "2009",

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doi = "10.1016/j.snb.2009.02.065",

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T1 - Electro-catalytic oxidation of methane at multi-walled carbon nanotubes-Nafion/nickel hydroxide modified nickel electrode

AU - Qiao, Jie

AU - Tang, Shengnan

AU - Tian, Yanni

AU - Shuang, Shaomin

AU - Dong, Chuan

AU - Choi, Martin M.F.

N1 - Funding Information: This work is supported by the Key Project of National Natural Science Foundation of China (50534100) and the Shanxi Province Graduate Student Innovative Plan (07010700).

PY - 2009/5/6

Y1 - 2009/5/6

N2 - A novel chemical modified nickel (Ni) electrode based on multi-walled carbon nanotubes (MWCNTs), Nafion film and nickel hydroxide has been successfully fabricated for methane (CH4) detection at ambient conditions. The morphology of the MWCNTs-Nafion/Ni(OH)2 film was characterized by transmission electron microscopy and the electrochemical properties of the Ni modified electrode were studied by cyclic voltammetry. The MWCNTs-Nafion/Ni(OH)2-Ni electrode showed good catalytic effect on the oxidation of CH4 in 1.0 M NaOH. In addition, the modified electrode was free from nitrogen and oxygen interferences. When differential pulse voltammetry was applied to the MWCNTs-Nafion/Ni(OH)2-Ni electrode, a good linear relationship between the oxidation peak current (i) and CH4 concentration (Cmethane) was obtained: i = 1.841Cmethane + 46.25, where i is in μA and Cmethane is in 0.0-16.0% (v/v). The relative standard deviation for detection of 3.0% (v/v) CH4 was 1.80% (n = 5). The proposed Ni modified electrode is anticipated to provide a promising technique to detect CH4 at ambient conditions.

AB - A novel chemical modified nickel (Ni) electrode based on multi-walled carbon nanotubes (MWCNTs), Nafion film and nickel hydroxide has been successfully fabricated for methane (CH4) detection at ambient conditions. The morphology of the MWCNTs-Nafion/Ni(OH)2 film was characterized by transmission electron microscopy and the electrochemical properties of the Ni modified electrode were studied by cyclic voltammetry. The MWCNTs-Nafion/Ni(OH)2-Ni electrode showed good catalytic effect on the oxidation of CH4 in 1.0 M NaOH. In addition, the modified electrode was free from nitrogen and oxygen interferences. When differential pulse voltammetry was applied to the MWCNTs-Nafion/Ni(OH)2-Ni electrode, a good linear relationship between the oxidation peak current (i) and CH4 concentration (Cmethane) was obtained: i = 1.841Cmethane + 46.25, where i is in μA and Cmethane is in 0.0-16.0% (v/v). The relative standard deviation for detection of 3.0% (v/v) CH4 was 1.80% (n = 5). The proposed Ni modified electrode is anticipated to provide a promising technique to detect CH4 at ambient conditions.

KW - Methane

KW - Multi-walled carbon nanotubes

KW - Nafion

KW - Nickel modified electrode

UR - https://www.scopus.com/pages/publications/64549106477

U2 - 10.1016/j.snb.2009.02.065

DO - 10.1016/j.snb.2009.02.065

M3 - Journal article

AN - SCOPUS:64549106477

SN - 0925-4005

VL - 138

SP - 402

EP - 407

JO - Sensors and Actuators B: Chemical

JF - Sensors and Actuators B: Chemical

IS - 2

ER -

Electro-catalytic oxidation of methane at multi-walled carbon nanotubes-Nafion/nickel hydroxide modified nickel electrode

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