Efficient near-infrared (NIR) luminescent PMMA-supported hybrid materials doped with tris-β-diketonate Ln3+ complex (Ln = Nd or Yb)

Zhao Zhang; Chao Yu; Lin Liu; Hongyan Li; Yani He; Xingqiang Lü; Rick W K WONG; Richard A. Jones

doi:10.1016/j.jphotochem.2015.08.022

Efficient near-infrared (NIR) luminescent PMMA-supported hybrid materials doped with tris-β-diketonate Ln³⁺ complex (Ln = Nd or Yb)

Zhao Zhang, Chao Yu, Lin Liu, Hongyan Li, Yani He, Xingqiang Lü^*, Rick W K WONG, Richard A. Jones

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

29 Citations (Scopus)

Abstract

Based on the self-assembly of a trifluorinated and acylpyrazole-modified β-diketonate ligand HL ((Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one), LnCl₃·6H₂O (Ln = La, Nd, Yb, Er, Gd, Eu or Tb) and 2,2′-bpy (2,2′-bipyridine), seven tris-β-diketonate complexes [Ln(L)₃(2,2′-bpy)] (Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4; Ln = Gd, 5; Ln = Eu, 6 or Ln = Tb, 7) were obtained, respectively, where the relatively lower ligands-based ³ππ^∗ energy level results in the good NIR luminescent properties ( = (0.068-1.12% and β;^b = 54-83%) for complexes 2 and 3. Especially for their series of PMMA-supported hybrid materials [Ln(L);bsubesubprime-bpy)]@PMMA, the doping not only causes the improved thermal stability and film-forming property, but also endows more efficient NIR luminescent property even at a doping concentration up to 1:200.

Original language	English
Pages (from-to)	104-113
Number of pages	10
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	314
DOIs	https://doi.org/10.1016/j.jphotochem.2015.08.022
Publication status	Published - 1 Jan 2016

Scopus Subject Areas

Chemistry(all)
Chemical Engineering(all)
Physics and Astronomy(all)

User-Defined Keywords

Energy transfer
NIR luminescent tris-β-diketonate Ln complexes
PMMA-supported doping hybrid materials
Trifluorinated and acylpyrazole-modified β-diketonate

Access to Document

10.1016/j.jphotochem.2015.08.022

Cite this

@article{d0084befa8d64559b0e384736dd45c32,

title = "Efficient near-infrared (NIR) luminescent PMMA-supported hybrid materials doped with tris-β-diketonate Ln3+ complex (Ln = Nd or Yb)",

abstract = "Based on the self-assembly of a trifluorinated and acylpyrazole-modified β-diketonate ligand HL ((Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one), LnCl3·6H2O (Ln = La, Nd, Yb, Er, Gd, Eu or Tb) and 2,2′-bpy (2,2′-bipyridine), seven tris-β-diketonate complexes [Ln(L)3(2,2′-bpy)] (Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4; Ln = Gd, 5; Ln = Eu, 6 or Ln = Tb, 7) were obtained, respectively, where the relatively lower ligands-based 3ππ∗ energy level results in the good NIR luminescent properties ( = (0.068-1.12% and β;b = 54-83%) for complexes 2 and 3. Especially for their series of PMMA-supported hybrid materials [Ln(L);bsubesubprime-bpy)]@PMMA, the doping not only causes the improved thermal stability and film-forming property, but also endows more efficient NIR luminescent property even at a doping concentration up to 1:200.",

keywords = "Energy transfer, NIR luminescent tris-β-diketonate Ln complexes, PMMA-supported doping hybrid materials, Trifluorinated and acylpyrazole-modified β-diketonate",

author = "Zhao Zhang and Chao Yu and Lin Liu and Hongyan Li and Yani He and Xingqiang L{\"u} and WONG, {Rick W K} and Jones, {Richard A.}",

note = "Funding Information: This work is funded by the National Natural Science Foundation ( 21373160 , 91222201 , 21173165 ), the Program for New Century Excellent Talents in University from the Ministry of Education of China ( NCET-10-0936 ), the research fund for the Doctoral Program ( 20116101110003 ) of Higher Education , the Science and Technology and Innovation Project ( 2012KTCQ01-37 ) of Shaanxi Province , Graduate Innovation and Creativity Fund (Visiting Learner) of Northwest University in PR of China. ",

year = "2016",

month = jan,

day = "1",

doi = "10.1016/j.jphotochem.2015.08.022",

language = "English",

volume = "314",

pages = "104--113",

journal = "Journal of Photochemistry and Photobiology A: Chemistry",

issn = "1010-6030",

publisher = "Elsevier",

}

TY - JOUR

T1 - Efficient near-infrared (NIR) luminescent PMMA-supported hybrid materials doped with tris-β-diketonate Ln3+ complex (Ln = Nd or Yb)

AU - Zhang, Zhao

AU - Yu, Chao

AU - Liu, Lin

AU - Li, Hongyan

AU - He, Yani

AU - Lü, Xingqiang

AU - WONG, Rick W K

AU - Jones, Richard A.

N1 - Funding Information: This work is funded by the National Natural Science Foundation ( 21373160 , 91222201 , 21173165 ), the Program for New Century Excellent Talents in University from the Ministry of Education of China ( NCET-10-0936 ), the research fund for the Doctoral Program ( 20116101110003 ) of Higher Education , the Science and Technology and Innovation Project ( 2012KTCQ01-37 ) of Shaanxi Province , Graduate Innovation and Creativity Fund (Visiting Learner) of Northwest University in PR of China.

PY - 2016/1/1

Y1 - 2016/1/1

N2 - Based on the self-assembly of a trifluorinated and acylpyrazole-modified β-diketonate ligand HL ((Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one), LnCl3·6H2O (Ln = La, Nd, Yb, Er, Gd, Eu or Tb) and 2,2′-bpy (2,2′-bipyridine), seven tris-β-diketonate complexes [Ln(L)3(2,2′-bpy)] (Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4; Ln = Gd, 5; Ln = Eu, 6 or Ln = Tb, 7) were obtained, respectively, where the relatively lower ligands-based 3ππ∗ energy level results in the good NIR luminescent properties ( = (0.068-1.12% and β;b = 54-83%) for complexes 2 and 3. Especially for their series of PMMA-supported hybrid materials [Ln(L);bsubesubprime-bpy)]@PMMA, the doping not only causes the improved thermal stability and film-forming property, but also endows more efficient NIR luminescent property even at a doping concentration up to 1:200.

AB - Based on the self-assembly of a trifluorinated and acylpyrazole-modified β-diketonate ligand HL ((Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one), LnCl3·6H2O (Ln = La, Nd, Yb, Er, Gd, Eu or Tb) and 2,2′-bpy (2,2′-bipyridine), seven tris-β-diketonate complexes [Ln(L)3(2,2′-bpy)] (Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4; Ln = Gd, 5; Ln = Eu, 6 or Ln = Tb, 7) were obtained, respectively, where the relatively lower ligands-based 3ππ∗ energy level results in the good NIR luminescent properties ( = (0.068-1.12% and β;b = 54-83%) for complexes 2 and 3. Especially for their series of PMMA-supported hybrid materials [Ln(L);bsubesubprime-bpy)]@PMMA, the doping not only causes the improved thermal stability and film-forming property, but also endows more efficient NIR luminescent property even at a doping concentration up to 1:200.

KW - Energy transfer

KW - NIR luminescent tris-β-diketonate Ln complexes

KW - PMMA-supported doping hybrid materials

KW - Trifluorinated and acylpyrazole-modified β-diketonate

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U2 - 10.1016/j.jphotochem.2015.08.022

DO - 10.1016/j.jphotochem.2015.08.022

M3 - Journal article

AN - SCOPUS:84940653810

SN - 1010-6030

VL - 314

SP - 104

EP - 113

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

ER -