Dual-nodal PMMA-supported Eu3 +-containing metallopolymer with high color-purity red luminescence

Xinyu Zhang; Zhao Zhang; Lin Liu; Chao Yu; Xingqiang Lü; Xunjin ZHU; Rick W K WONG; Richard A. Jones

doi:10.1016/j.inoche.2015.07.026

Dual-nodal PMMA-supported Eu^{3 +}-containing metallopolymer with high color-purity red luminescence

Xinyu Zhang, Zhao Zhang, Lin Liu, Chao Yu, Xingqiang Lü^*, Xunjin ZHU, Rick W K WONG, Richard A. Jones

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

5 Citations (Scopus)

Abstract

Based on chemical grafting of the complex monomer [Eu(TTA)₃(4-vinyl-Py)₂] (HTTA = 2-thenoyltrifluoroacetylacetate, 4-vinyl-Py = 4-vinyl-pyridine) with two active vinyl groups and MMA (methyl methacrylate), the dual-nodal PMMA-supported metallopolymers with high color-purity Eu^{3 +}-based luminescence are obtained. The physical properties show that their luminescent properties (τ_obs = 494-552 μs and Φ_Eu^L = 50-55%) are distinctively enhanced from copolymerization in comparison with those (τ_obs = 470 μs and Φ_Eu^L = 44%) of the complex monomer besides the improvement of thermal-stabilities.

Original language	English
Pages (from-to)	51-53
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	60
DOIs	https://doi.org/10.1016/j.inoche.2015.07.026
Publication status	Published - 17 Aug 2015

User-Defined Keywords

Dual-nodal PMMA-supported metallopolymer
High color-purity Eu-based luminescence
Tris-β-diketonate Eu-complex

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10.1016/j.inoche.2015.07.026

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@article{1e6b0c9b4a9b4231a210d42840f71baf,

title = "Dual-nodal PMMA-supported Eu3 +-containing metallopolymer with high color-purity red luminescence",

abstract = "Based on chemical grafting of the complex monomer [Eu(TTA)3(4-vinyl-Py)2] (HTTA = 2-thenoyltrifluoroacetylacetate, 4-vinyl-Py = 4-vinyl-pyridine) with two active vinyl groups and MMA (methyl methacrylate), the dual-nodal PMMA-supported metallopolymers with high color-purity Eu3 +-based luminescence are obtained. The physical properties show that their luminescent properties (τobs = 494-552 μs and ΦEuL = 50-55%) are distinctively enhanced from copolymerization in comparison with those (τobs = 470 μs and ΦEuL = 44%) of the complex monomer besides the improvement of thermal-stabilities.",

keywords = "Dual-nodal PMMA-supported metallopolymer, High color-purity Eu-based luminescence, Tris-β-diketonate Eu-complex",

author = "Xinyu Zhang and Zhao Zhang and Lin Liu and Chao Yu and Xingqiang L{\"u} and Xunjin ZHU and WONG, {Rick W K} and Jones, {Richard A.}",

note = "Funding Information: This work is funded by NNSF ( 21373160 , 91222201 , 21173165 ), NCET-10-0936 , 2012KTCQ01-37 , and 2013JQ2002 of Shaanxi Province and YZZ12038 of Northwest University in P. R. of China. ",

year = "2015",

month = aug,

day = "17",

doi = "10.1016/j.inoche.2015.07.026",

language = "English",

volume = "60",

pages = "51--53",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Dual-nodal PMMA-supported Eu3 +-containing metallopolymer with high color-purity red luminescence

AU - Zhang, Xinyu

AU - Zhang, Zhao

AU - Liu, Lin

AU - Yu, Chao

AU - Lü, Xingqiang

AU - ZHU, Xunjin

AU - WONG, Rick W K

AU - Jones, Richard A.

N1 - Funding Information: This work is funded by NNSF ( 21373160 , 91222201 , 21173165 ), NCET-10-0936 , 2012KTCQ01-37 , and 2013JQ2002 of Shaanxi Province and YZZ12038 of Northwest University in P. R. of China.

PY - 2015/8/17

Y1 - 2015/8/17

N2 - Based on chemical grafting of the complex monomer [Eu(TTA)3(4-vinyl-Py)2] (HTTA = 2-thenoyltrifluoroacetylacetate, 4-vinyl-Py = 4-vinyl-pyridine) with two active vinyl groups and MMA (methyl methacrylate), the dual-nodal PMMA-supported metallopolymers with high color-purity Eu3 +-based luminescence are obtained. The physical properties show that their luminescent properties (τobs = 494-552 μs and ΦEuL = 50-55%) are distinctively enhanced from copolymerization in comparison with those (τobs = 470 μs and ΦEuL = 44%) of the complex monomer besides the improvement of thermal-stabilities.

AB - Based on chemical grafting of the complex monomer [Eu(TTA)3(4-vinyl-Py)2] (HTTA = 2-thenoyltrifluoroacetylacetate, 4-vinyl-Py = 4-vinyl-pyridine) with two active vinyl groups and MMA (methyl methacrylate), the dual-nodal PMMA-supported metallopolymers with high color-purity Eu3 +-based luminescence are obtained. The physical properties show that their luminescent properties (τobs = 494-552 μs and ΦEuL = 50-55%) are distinctively enhanced from copolymerization in comparison with those (τobs = 470 μs and ΦEuL = 44%) of the complex monomer besides the improvement of thermal-stabilities.

KW - Dual-nodal PMMA-supported metallopolymer

KW - High color-purity Eu-based luminescence

KW - Tris-β-diketonate Eu-complex

UR - http://www.scopus.com/inward/record.url?scp=84939503291&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2015.07.026

DO - 10.1016/j.inoche.2015.07.026

M3 - Journal article

AN - SCOPUS:84939503291

SN - 1387-7003

VL - 60

SP - 51

EP - 53

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Dual-nodal PMMA-supported Eu^{3 +}-containing metallopolymer with high color-purity red luminescence

Abstract

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