Direct NMR and luminescence observation of water exchange at cationic ytterbium and europium centres

Andrei S. Batsanov; Andrew Beeby; James I. Bruce; Judith A.K. Howard; Alan M. Kenwright; David Parker

doi:10.1039/a902260k

Direct NMR and luminescence observation of water exchange at cationic ytterbium and europium centres

Andrei S. Batsanov
, Andrew Beeby
, James I. Bruce
, Judith A.K. Howard
, Alan M. Kenwright
, David Parker^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

51 Citations (Scopus)

Abstract

Cationic chiral Yb and Eu tetra-amide complexes, have been studied by VT NMR, luminescence and crystallography: the rate of dissociation of water is about 500 times faster at Yb than at the square antiprismatic Eu centre.

Original language	English
Pages (from-to)	1011-1012
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/a902260k
Publication status	Published - 7 Jun 1999

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@article{47781acb30ef4d99a2a108068fec43ee,

title = "Direct NMR and luminescence observation of water exchange at cationic ytterbium and europium centres",

abstract = "Cationic chiral Yb and Eu tetra-amide complexes, have been studied by VT NMR, luminescence and crystallography: the rate of dissociation of water is about 500 times faster at Yb than at the square antiprismatic Eu centre.",

author = "Batsanov, \{Andrei S.\} and Andrew Beeby and Bruce, \{James I.\} and Howard, \{Judith A.K.\} and Kenwright, \{Alan M.\} and David Parker",

year = "1999",

month = jun,

day = "7",

doi = "10.1039/a902260k",

language = "English",

pages = "1011--1012",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Direct NMR and luminescence observation of water exchange at cationic ytterbium and europium centres

AU - Batsanov, Andrei S.

AU - Beeby, Andrew

AU - Bruce, James I.

AU - Howard, Judith A.K.

AU - Kenwright, Alan M.

AU - Parker, David

PY - 1999/6/7

Y1 - 1999/6/7

N2 - Cationic chiral Yb and Eu tetra-amide complexes, have been studied by VT NMR, luminescence and crystallography: the rate of dissociation of water is about 500 times faster at Yb than at the square antiprismatic Eu centre.

AB - Cationic chiral Yb and Eu tetra-amide complexes, have been studied by VT NMR, luminescence and crystallography: the rate of dissociation of water is about 500 times faster at Yb than at the square antiprismatic Eu centre.

UR - https://www.scopus.com/pages/publications/0033532675

U2 - 10.1039/a902260k

DO - 10.1039/a902260k

M3 - Journal article

AN - SCOPUS:0033532675

SN - 1359-7345

SP - 1011

EP - 1012

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Direct NMR and luminescence observation of water exchange at cationic ytterbium and europium centres

Abstract

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