Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

Andrei S. Batsanov; Andrei V. Churakov; Morag A.M. Easson; Linda J. Govenlock; Judith A.K. Howard; Janet M. Moloney; David Parker

doi:10.1039/a807142j

Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

Andrei S. Batsanov, Andrei V. Churakov, Morag A.M. Easson, Linda J. Govenlock, Judith A.K. Howard, Janet M. Moloney, David Parker^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

9 Citations (Scopus)

Abstract

Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of Cu^I, Cu^II, Ni^II and Zn^II has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.

Original language	English
Pages (from-to)	323-329
Number of pages	7
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/a807142j
Publication status	Published - 7 Feb 1999

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Batsanov, A. S., Churakov, A. V., Easson, M. A. M., Govenlock, L. J., Howard, J. A. K., Moloney, J. M., & Parker, D. (1999). Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry. Journal of the Chemical Society - Dalton Transactions, (3), 323-329. https://doi.org/10.1039/a807142j

@article{a712eba917874bfa9bef0d9fbc92b53f,

title = "Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry",

abstract = "Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of CuI, CuII, NiII and ZnII has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.",

author = "Batsanov, {Andrei S.} and Churakov, {Andrei V.} and Easson, {Morag A.M.} and Govenlock, {Linda J.} and Howard, {Judith A.K.} and Moloney, {Janet M.} and David Parker",

note = "We thank EPSRC for studentship support, the Commissioners of the 1851 Exhibition for a Fellowship (to L. J. G.), the Leverhulme Trust for a visiting fellowship (to A. S. B.) and the Royal Society for support (to A. V. C.).",

year = "1999",

month = feb,

day = "7",

doi = "10.1039/a807142j",

language = "English",

pages = "323--329",

journal = " Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "3",

}

Batsanov, AS, Churakov, AV, Easson, MAM, Govenlock, LJ, Howard, JAK, Moloney, JM & Parker, D 1999, 'Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry', Journal of the Chemical Society - Dalton Transactions, no. 3, pp. 323-329. https://doi.org/10.1039/a807142j

Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry. / Batsanov, Andrei S.; Churakov, Andrei V.; Easson, Morag A.M. et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 3, 07.02.1999, p. 323-329.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Dimethylthiophosphoryl hydrazone ligands and their copper complexes

T2 - Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

AU - Batsanov, Andrei S.

AU - Churakov, Andrei V.

AU - Easson, Morag A.M.

AU - Govenlock, Linda J.

AU - Howard, Judith A.K.

AU - Moloney, Janet M.

AU - Parker, David

N1 - We thank EPSRC for studentship support, the Commissioners of the 1851 Exhibition for a Fellowship (to L. J. G.), the Leverhulme Trust for a visiting fellowship (to A. S. B.) and the Royal Society for support (to A. V. C.).

PY - 1999/2/7

Y1 - 1999/2/7

N2 - Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of CuI, CuII, NiII and ZnII has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.

AB - Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of CuI, CuII, NiII and ZnII has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.

UR - http://www.scopus.com/inward/record.url?scp=33846973421&partnerID=8YFLogxK

U2 - 10.1039/a807142j

DO - 10.1039/a807142j

M3 - Journal article

AN - SCOPUS:33846973421

SN - 0300-9246

SP - 323

EP - 329

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 3

ER -

Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

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