Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

Andrei S. Batsanov; Andrei V. Churakov; Morag A.M. Easson; Linda J. Govenlock; Judith A.K. Howard; Janet M. Moloney; David Parker

doi:10.1039/a807142j

Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

Andrei S. Batsanov
, Andrei V. Churakov
, Morag A.M. Easson
, Linda J. Govenlock
, Judith A.K. Howard
, Janet M. Moloney
, David Parker^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

9 Citations (Scopus)

Abstract

Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of Cu^I, Cu^II, Ni^II and Zn^II has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.

Original language	English
Pages (from-to)	323-329
Number of pages	7
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/a807142j
Publication status	Published - 7 Feb 1999

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Batsanov, A. S., Churakov, A. V., Easson, M. A. M., Govenlock, L. J., Howard, J. A. K., Moloney, J. M., & Parker, D. (1999). Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry. Journal of the Chemical Society - Dalton Transactions, (3), 323-329. https://doi.org/10.1039/a807142j

@article{a712eba917874bfa9bef0d9fbc92b53f,

title = "Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry",

abstract = "Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of CuI, CuII, NiII and ZnII has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.",

author = "Batsanov, \{Andrei S.\} and Churakov, \{Andrei V.\} and Easson, \{Morag A.M.\} and Govenlock, \{Linda J.\} and Howard, \{Judith A.K.\} and Moloney, \{Janet M.\} and David Parker",

note = "We thank EPSRC for studentship support, the Commissioners of the 1851 Exhibition for a Fellowship (to L. J. G.), the Leverhulme Trust for a visiting fellowship (to A. S. B.) and the Royal Society for support (to A. V. C.).",

year = "1999",

month = feb,

day = "7",

doi = "10.1039/a807142j",

language = "English",

pages = "323--329",

journal = " Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "3",

}

Batsanov, AS, Churakov, AV, Easson, MAM, Govenlock, LJ, Howard, JAK, Moloney, JM & Parker, D 1999, 'Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry', Journal of the Chemical Society - Dalton Transactions, no. 3, pp. 323-329. https://doi.org/10.1039/a807142j

Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry. / Batsanov, Andrei S.; Churakov, Andrei V.; Easson, Morag A.M. et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 3, 07.02.1999, p. 323-329.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Dimethylthiophosphoryl hydrazone ligands and their copper complexes

T2 - Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

AU - Batsanov, Andrei S.

AU - Churakov, Andrei V.

AU - Easson, Morag A.M.

AU - Govenlock, Linda J.

AU - Howard, Judith A.K.

AU - Moloney, Janet M.

AU - Parker, David

N1 - We thank EPSRC for studentship support, the Commissioners of the 1851 Exhibition for a Fellowship (to L. J. G.), the Leverhulme Trust for a visiting fellowship (to A. S. B.) and the Royal Society for support (to A. V. C.).

PY - 1999/2/7

Y1 - 1999/2/7

N2 - Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of CuI, CuII, NiII and ZnII has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.

AB - Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of CuI, CuII, NiII and ZnII has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1:1 and 2:1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride-bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.

UR - https://www.scopus.com/pages/publications/33846973421

U2 - 10.1039/a807142j

DO - 10.1039/a807142j

M3 - Journal article

AN - SCOPUS:33846973421

SN - 0300-9246

SP - 323

EP - 329

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 3

ER -

Dimethylthiophosphoryl hydrazone ligands and their copper complexes: Crystal structures and analysis of their solution complexation behaviour by electrospray mass spectrometry

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