Development and advancement of iridium(III)-based complexes for photocatalytic hydrogen evolution

Daniel Nnaemaka Tritton, Fung Kit Tang, Govardhana Babu Bodedla, Fu Wa Lee, Chak Shing Kwan, Ken Cham Fai Leung*, Xunjin Zhu, Wai Yeung Wong*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

Abstract

Among the vast array of transition metal complexes which have been previously reported, organometallic compounds based on iridium(III) and relevant metal complexes have been shown to possess particularly interesting features; including a wide range of versatile chemical structures, unique photophysical properties and, perhaps most importantly, outstanding photocatalytic capabilities. This review surveys the design and evaluation of these compounds as photocatalysts/photosensitizers in systems for photocatalytic hydrogen evolution (PHE) reactions. Photo-redox mechanisms are addressed, and structure-catalytic activity relationships are identified to guide the future design of more efficient and robust photocatalytic systems.

Original languageEnglish
Article number214390
JournalCoordination Chemistry Reviews
Volume459
DOIs
Publication statusPublished - 15 May 2022

Scopus Subject Areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

User-Defined Keywords

  • Catalytic system
  • Hydrogen
  • Iridium
  • Photosensitizer
  • Water reduction

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