TY - JOUR
T1 - DDT, Chlordane, and Hexachlorobenzene in the Air of the Pearl River Delta Revisited: A Tale of Source, History, and Monsoon
AU - Tian, Lele
AU - Li, Jing
AU - Zhao, Shizhen
AU - Tang, Jiao
AU - Li, Jun
AU - Guo, Hai
AU - Liu, Xin
AU - Zhong, Guangcai
AU - Xu, Yue
AU - Lin, Tian
AU - Lyv, Xiaopu
AU - Chen, Duohong
AU - Li, Kechang
AU - Shen, Jin
AU - Zhang, Gan
N1 - This work was supported by the National Key R&D Program of China (2017YFC0212000), Local Innovative Scientific Research Team Project of Guangdong “Pearl River Talents Plan” (2017BT01Z134), Guangdong Foundation for Program of Science and Technology Research (2019B121205006,2019A1515011254, and 2021A1515012177), and Tuguangchi Award for Excellent Young Scholar GIG and the State Key Laboratory of Organic Geochemistry, GIGCAS (SKLOG2020-9).
PY - 2021/7/20
Y1 - 2021/7/20
N2 - Although organochlorine pesticides (OCPs) have been banned for more than three decades, their concentrations have only decreased gradually. This may be largely attributable to their environmental persistence, illegal application, and exemption usage. This study assessed the historic and current regional context for dichlorodiphenyltrichloroethane (DDT), chlordane, and hexachlorobenzene (HCB), which were added to the Stockholm Convention in 2001. An air sampling campaign was carried out in 2018 in nine cities of the Pearl River Delta (PRD), where the historical OCP application was the most intensive in China. Different seasonalities were observed: DDT exhibited higher concentrations in summer than in winter; chlordane showed less seasonal variation, whereas HCB was higher in winter. The unique coupling of summer monsoon with DDT-infused paint usage, winter monsoon with HCB-combustion emission, and local chlordane emission jointly presents a dynamic picture of these OCPs in the PRD air. We used the BETR Global model to back-calculate annual local emissions, which accounted for insignificant contributions to the nationally documented production (
AB - Although organochlorine pesticides (OCPs) have been banned for more than three decades, their concentrations have only decreased gradually. This may be largely attributable to their environmental persistence, illegal application, and exemption usage. This study assessed the historic and current regional context for dichlorodiphenyltrichloroethane (DDT), chlordane, and hexachlorobenzene (HCB), which were added to the Stockholm Convention in 2001. An air sampling campaign was carried out in 2018 in nine cities of the Pearl River Delta (PRD), where the historical OCP application was the most intensive in China. Different seasonalities were observed: DDT exhibited higher concentrations in summer than in winter; chlordane showed less seasonal variation, whereas HCB was higher in winter. The unique coupling of summer monsoon with DDT-infused paint usage, winter monsoon with HCB-combustion emission, and local chlordane emission jointly presents a dynamic picture of these OCPs in the PRD air. We used the BETR Global model to back-calculate annual local emissions, which accounted for insignificant contributions to the nationally documented production (
KW - organochlorine pesticides
KW - Pearl River Delta
KW - back-calculated emission
KW - multimedia fate model
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85110978886&origin=inward
U2 - 10.1021/acs.est.1c01045
DO - 10.1021/acs.est.1c01045
M3 - Journal article
SN - 0013-936X
VL - 55
SP - 9740
EP - 9749
JO - Environmental Science and Technology
JF - Environmental Science and Technology
IS - 14
ER -