Dawson-type polyoxometalate-based oligomeric Hg(II)-acetylide hybrid: Synthesis, characterization and materials properties

Li Liu; Lei Hu; Qian Liu; Shi Zhong Liu; Fa Bao Li; Ling Li; Liang Peng; Deng Hui Yao; Wai Yeung WONG; Zu Liang Du

doi:10.1016/j.jorganchem.2015.02.039

Dawson-type polyoxometalate-based oligomeric Hg(II)-acetylide hybrid: Synthesis, characterization and materials properties

Li Liu^*, Lei Hu, Qian Liu, Shi Zhong Liu, Fa Bao Li, Ling Li, Liang Peng, Deng Hui Yao, Wai Yeung WONG, Zu Liang Du

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

5 Citations (Scopus)

Abstract

Abstract A new synthetic scheme for preparing Dawson-type polyoxometalate (POM) based inorganic-organic hybrid material is reported. A new heteropolytungstate-based oligomeric Hg(II) acetylide inorganic-organic hybrid compound (OHgOD) was prepared by Hagihara's dehydrohalogenating coupling of a diacetylene POM hybrid with diphosphoryl functionality and mercury(II) halide. This method provides a rigid covalent linkage between the POM and the organometallic Hg(II) acetylide moiety. The materials properties of hybrid LB film derived from the hybrid were studied.

Original language	English
Article number	18940
Pages (from-to)	102-108
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	792
DOIs	https://doi.org/10.1016/j.jorganchem.2015.02.039
Publication status	Published - 23 Dec 2015

User-Defined Keywords

Acetylide
Inorganic-organic hybrid
LB film
Mercury
Polyoxometalate

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10.1016/j.jorganchem.2015.02.039

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@article{b229ebab3c6d4c6492efb416f927a183,

title = "Dawson-type polyoxometalate-based oligomeric Hg(II)-acetylide hybrid: Synthesis, characterization and materials properties",

abstract = "Abstract A new synthetic scheme for preparing Dawson-type polyoxometalate (POM) based inorganic-organic hybrid material is reported. A new heteropolytungstate-based oligomeric Hg(II) acetylide inorganic-organic hybrid compound (OHgOD) was prepared by Hagihara's dehydrohalogenating coupling of a diacetylene POM hybrid with diphosphoryl functionality and mercury(II) halide. This method provides a rigid covalent linkage between the POM and the organometallic Hg(II) acetylide moiety. The materials properties of hybrid LB film derived from the hybrid were studied.",

keywords = "Acetylide, Inorganic-organic hybrid, LB film, Mercury, Polyoxometalate",

author = "Li Liu and Lei Hu and Qian Liu and Liu, {Shi Zhong} and Li, {Fa Bao} and Ling Li and Liang Peng and Yao, {Deng Hui} and WONG, {Wai Yeung} and Du, {Zu Liang}",

note = "This work was supported by the National Natural Science Foundation of China (Nos. 21071049 and 51373145), Natural Science Foundation of Hubei Province of China (2013CFA087), Hubei Province High-End Talent Training Program, Natural Science Fund for Creative Research Groups of Hubei Province of China (No. 2014CFA015), and Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province (No. 201310512012). ",

year = "2015",

month = dec,

day = "23",

doi = "10.1016/j.jorganchem.2015.02.039",

language = "English",

volume = "792",

pages = "102--108",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Dawson-type polyoxometalate-based oligomeric Hg(II)-acetylide hybrid

T2 - Synthesis, characterization and materials properties

AU - Liu, Li

AU - Hu, Lei

AU - Liu, Qian

AU - Liu, Shi Zhong

AU - Li, Fa Bao

AU - Li, Ling

AU - Peng, Liang

AU - Yao, Deng Hui

AU - WONG, Wai Yeung

AU - Du, Zu Liang

N1 - This work was supported by the National Natural Science Foundation of China (Nos. 21071049 and 51373145), Natural Science Foundation of Hubei Province of China (2013CFA087), Hubei Province High-End Talent Training Program, Natural Science Fund for Creative Research Groups of Hubei Province of China (No. 2014CFA015), and Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province (No. 201310512012).

PY - 2015/12/23

Y1 - 2015/12/23

N2 - Abstract A new synthetic scheme for preparing Dawson-type polyoxometalate (POM) based inorganic-organic hybrid material is reported. A new heteropolytungstate-based oligomeric Hg(II) acetylide inorganic-organic hybrid compound (OHgOD) was prepared by Hagihara's dehydrohalogenating coupling of a diacetylene POM hybrid with diphosphoryl functionality and mercury(II) halide. This method provides a rigid covalent linkage between the POM and the organometallic Hg(II) acetylide moiety. The materials properties of hybrid LB film derived from the hybrid were studied.

AB - Abstract A new synthetic scheme for preparing Dawson-type polyoxometalate (POM) based inorganic-organic hybrid material is reported. A new heteropolytungstate-based oligomeric Hg(II) acetylide inorganic-organic hybrid compound (OHgOD) was prepared by Hagihara's dehydrohalogenating coupling of a diacetylene POM hybrid with diphosphoryl functionality and mercury(II) halide. This method provides a rigid covalent linkage between the POM and the organometallic Hg(II) acetylide moiety. The materials properties of hybrid LB film derived from the hybrid were studied.

KW - Acetylide

KW - Inorganic-organic hybrid

KW - LB film

KW - Mercury

KW - Polyoxometalate

UR - http://www.scopus.com/inward/record.url?scp=84938953812&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2015.02.039

DO - 10.1016/j.jorganchem.2015.02.039

M3 - Journal article

AN - SCOPUS:84938953812

SN - 0022-328X

VL - 792

SP - 102

EP - 108

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

M1 - 18940

ER -

Dawson-type polyoxometalate-based oligomeric Hg(II)-acetylide hybrid: Synthesis, characterization and materials properties

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