Dalton communications. Synthesis and crystal structure of [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}]

Rick W K WONG; Tao Jiang; Wing Tak Wong

doi:10.1039/DT9950003087

Dalton communications. Synthesis and crystal structure of [RuCl₂(PPh₃){N(SiMe₃)C(Ph)NH(PPh₂)}]

Rick W K WONG^*, Tao Jiang, Wing Tak Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

7 Citations (Scopus)

Abstract

The interaction of (Ph₂P)NC(Ph)[N(SiMe₃)₂] with 1 equivalent of [RuCl₂(PPh₃)₃] in tetrahydrofuran gave [RuCl₂(PPh₃){N(SiMe₃)C(Ph)NH(PPh₂)}] whose structure established by X-ray crystallography suggests the presence of a γ-agostic interaction between ruthenium and one of the methyl groups of the N(SiMe₃) imino group.

Original language	English
Pages (from-to)	3087-3088
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	18
DOIs	https://doi.org/10.1039/DT9950003087
Publication status	Published - 1995

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title = "Dalton communications. Synthesis and crystal structure of [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}]",

abstract = "The interaction of (Ph2P)NC(Ph)[N(SiMe3)2] with 1 equivalent of [RuCl2(PPh3)3] in tetrahydrofuran gave [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}] whose structure established by X-ray crystallography suggests the presence of a γ-agostic interaction between ruthenium and one of the methyl groups of the N(SiMe3) imino group.",

author = "WONG, {Rick W K} and Tao Jiang and Wong, {Wing Tak}",

year = "1995",

doi = "10.1039/DT9950003087",

language = "English",

pages = "3087--3088",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "18",

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TY - JOUR

T1 - Dalton communications. Synthesis and crystal structure of [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}]

AU - WONG, Rick W K

AU - Jiang, Tao

AU - Wong, Wing Tak

PY - 1995

Y1 - 1995

N2 - The interaction of (Ph2P)NC(Ph)[N(SiMe3)2] with 1 equivalent of [RuCl2(PPh3)3] in tetrahydrofuran gave [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}] whose structure established by X-ray crystallography suggests the presence of a γ-agostic interaction between ruthenium and one of the methyl groups of the N(SiMe3) imino group.

AB - The interaction of (Ph2P)NC(Ph)[N(SiMe3)2] with 1 equivalent of [RuCl2(PPh3)3] in tetrahydrofuran gave [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}] whose structure established by X-ray crystallography suggests the presence of a γ-agostic interaction between ruthenium and one of the methyl groups of the N(SiMe3) imino group.

UR - http://www.scopus.com/inward/record.url?scp=37049070915&partnerID=8YFLogxK

U2 - 10.1039/DT9950003087

DO - 10.1039/DT9950003087

M3 - Journal article

AN - SCOPUS:37049070915

SN - 0300-9246

SP - 3087

EP - 3088

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 18

ER -

Dalton communications. Synthesis and crystal structure of [RuCl₂(PPh₃){N(SiMe₃)C(Ph)NH(PPh₂)}]

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