Controlling the variation of axial water exchange rates in macrocyclic lanthanide(iii) complexes

Silvio Aime; Alessandro Barge; Andrei S. Batsanov; Mauro Botta; Daniela Delli Castelli; Franco Fedeli; Armando Mortillaro; David Parker; Horst Puschmann

doi:10.1039/b202862j

Controlling the variation of axial water exchange rates in macrocyclic lanthanide(iii) complexes

Silvio Aime^*, Alessandro Barge, Andrei S. Batsanov, Mauro Botta, Daniela Delli Castelli, Franco Fedeli, Armando Mortillaro, David Parker^*, Horst Puschmann

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

79 Citations (Scopus)

Abstract

The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.

Original language	English
Pages (from-to)	1120-1121
Number of pages	2
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/b202862j
Publication status	Published - 19 Apr 2002

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title = "Controlling the variation of axial water exchange rates in macrocyclic lanthanide(iii) complexes",

abstract = "The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.",

author = "Silvio Aime and Alessandro Barge and Batsanov, {Andrei S.} and Mauro Botta and Castelli, {Daniela Delli} and Franco Fedeli and Armando Mortillaro and David Parker and Horst Puschmann",

note = "We thank EPSRC, MURST (PRIN) and the EC COST Action D-18 for support. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2002",

year = "2002",

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doi = "10.1039/b202862j",

language = "English",

pages = "1120--1121",

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T1 - Controlling the variation of axial water exchange rates in macrocyclic lanthanide(iii) complexes

AU - Aime, Silvio

AU - Barge, Alessandro

AU - Batsanov, Andrei S.

AU - Botta, Mauro

AU - Castelli, Daniela Delli

AU - Fedeli, Franco

AU - Mortillaro, Armando

AU - Parker, David

AU - Puschmann, Horst

PY - 2002/4/19

Y1 - 2002/4/19

N2 - The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.

AB - The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.

UR - http://www.scopus.com/inward/record.url?scp=0037161776&partnerID=8YFLogxK

U2 - 10.1039/b202862j

DO - 10.1039/b202862j

M3 - Journal article

C2 - 12122694

AN - SCOPUS:0037161776

SN - 1359-7345

SP - 1120

EP - 1121

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Controlling the variation of axial water exchange rates in macrocyclic lanthanide(iii) complexes

Abstract

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