Construction of 1-D 4f and 3d-4f coordination polymers with flexible Schiff base ligands

Xiaoping Yang; Daniel Lam; Christopher Chan; Julie M. Stanley; Richard A. Jones; Bradley J. Holliday; Rick W K WONG

doi:10.1039/c1dt11036e

Construction of 1-D 4f and 3d-4f coordination polymers with flexible Schiff base ligands

Xiaoping Yang
, Daniel Lam
, Christopher Chan
, Julie M. Stanley
, Richard A. Jones^*
, Bradley J. Holliday
, Rick W K WONG

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

46 Citations (Scopus)

Abstract

Three new lanthanide 1-D coordination polymers ({[Ln ₂(H ₂L)(OAc) ₆]·EtOH·2H ₂O} _n (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc) ₂(H ₂O)} _n (3)) and a heterobinuclear complex [YbNiLCl ₃(H ₂O) ₃] (4) are reported which are formed from salen type Schiff-base ligands H ₂L (H ₂L = N,N′-bis(3-methoxysalicylidene)butane-1,4-diamine). The polymeric structures are formed by bridging H ₂L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1-4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.

Original language	English
Pages (from-to)	9795-9801
Number of pages	7
Journal	Dalton Transactions
Volume	40
Issue number	38
DOIs	https://doi.org/10.1039/c1dt11036e
Publication status	Published - 14 Oct 2011

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@article{a705c4a229cf4ad28feda8d1891cd038,

title = "Construction of 1-D 4f and 3d-4f coordination polymers with flexible Schiff base ligands",

abstract = "Three new lanthanide 1-D coordination polymers (\{[Ln 2(H 2L)(OAc) 6]·EtOH·2H 2O\} n (Ln = Eu (1), Er (2)) and \{YbNiLCl(OAc) 2(H 2O)\} n (3)) and a heterobinuclear complex [YbNiLCl 3(H 2O) 3] (4) are reported which are formed from salen type Schiff-base ligands H 2L (H 2L = N,N′-bis(3-methoxysalicylidene)butane-1,4-diamine). The polymeric structures are formed by bridging H 2L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1-4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.",

author = "Xiaoping Yang and Daniel Lam and Christopher Chan and Stanley, \{Julie M.\} and Jones, \{Richard A.\} and Holliday, \{Bradley J.\} and WONG, \{Rick W K\}",

note = "The authors acknowledge the Freshman Research Initiative, funded in part by HHMI Undergraduate Science Education Award (52005907) and the National Science Foundation (CHE-0629136). Single crystal X-ray data were collected using instrumentation purchased with funds provided by the National Science Foundation (CHE-0741973). BJH wishes to acknowledge the Welch Foundation (F-1631), the Petroleum Research Fund administered by the American Chemical Society (47022-G3), the National Science Foundation (CHE-0639239, CHE-0847763), the American Heart Association (0765078Y), and the UT-CNM and UT-Austin for financial support of this research. RAJ wishes to acknowledge the Welch Foundation (F-816). WKW wishes to thank Hong Kong Baptist University (FRG/06-07/II-16) and the Hong Kong Research Grants Council (HKBU 202407) financial support.",

year = "2011",

month = oct,

day = "14",

doi = "10.1039/c1dt11036e",

language = "English",

volume = "40",

pages = "9795--9801",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "38",

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TY - JOUR

T1 - Construction of 1-D 4f and 3d-4f coordination polymers with flexible Schiff base ligands

AU - Yang, Xiaoping

AU - Lam, Daniel

AU - Chan, Christopher

AU - Stanley, Julie M.

AU - Jones, Richard A.

AU - Holliday, Bradley J.

AU - WONG, Rick W K

N1 - The authors acknowledge the Freshman Research Initiative, funded in part by HHMI Undergraduate Science Education Award (52005907) and the National Science Foundation (CHE-0629136). Single crystal X-ray data were collected using instrumentation purchased with funds provided by the National Science Foundation (CHE-0741973). BJH wishes to acknowledge the Welch Foundation (F-1631), the Petroleum Research Fund administered by the American Chemical Society (47022-G3), the National Science Foundation (CHE-0639239, CHE-0847763), the American Heart Association (0765078Y), and the UT-CNM and UT-Austin for financial support of this research. RAJ wishes to acknowledge the Welch Foundation (F-816). WKW wishes to thank Hong Kong Baptist University (FRG/06-07/II-16) and the Hong Kong Research Grants Council (HKBU 202407) financial support.

PY - 2011/10/14

Y1 - 2011/10/14

N2 - Three new lanthanide 1-D coordination polymers ({[Ln 2(H 2L)(OAc) 6]·EtOH·2H 2O} n (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc) 2(H 2O)} n (3)) and a heterobinuclear complex [YbNiLCl 3(H 2O) 3] (4) are reported which are formed from salen type Schiff-base ligands H 2L (H 2L = N,N′-bis(3-methoxysalicylidene)butane-1,4-diamine). The polymeric structures are formed by bridging H 2L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1-4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.

AB - Three new lanthanide 1-D coordination polymers ({[Ln 2(H 2L)(OAc) 6]·EtOH·2H 2O} n (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc) 2(H 2O)} n (3)) and a heterobinuclear complex [YbNiLCl 3(H 2O) 3] (4) are reported which are formed from salen type Schiff-base ligands H 2L (H 2L = N,N′-bis(3-methoxysalicylidene)butane-1,4-diamine). The polymeric structures are formed by bridging H 2L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1-4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.

UR - https://www.scopus.com/pages/publications/80055060268

U2 - 10.1039/c1dt11036e

DO - 10.1039/c1dt11036e

M3 - Journal article

C2 - 21874186

AN - SCOPUS:80055060268

SN - 1477-9226

VL - 40

SP - 9795

EP - 9801

JO - Dalton Transactions

JF - Dalton Transactions

IS - 38

ER -

Construction of 1-D 4f and 3d-4f coordination polymers with flexible Schiff base ligands

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