Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: Direct formation of enantiopure systems for circularly polarised luminescence applications

  • Nicholas H. Evans
  • , Rachel Carr
  • , Martina Delbianco
  • , Robert Pal
  • , Dmitry S. Yufit
  • , David Parker*
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

27 Citations (Scopus)

Abstract

Mono-C-substitution of the 1,4,7-triazacyclononane ring induces formation of single enantiomers of Eu(iii) complexes with nonadentate N6O 3 ligands. The absolute configuration of each complex is determined by the stereogenicity of the C-substituent, revealed by comparison of the sign and sequence of CPL transitions for a series of complexes.

Original languageEnglish
Pages (from-to)15610-15616
Number of pages7
JournalDalton Transactions
Volume42
Issue number44
Early online date13 Sept 2013
DOIs
Publication statusPublished - 28 Nov 2013

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