TY - JOUR
T1 - Comparative study of mono- and di-substituted 14-crown-4 derivatives as lithium ionophores
AU - Kataky, Ritu
AU - Nicholson, Patrick E.
AU - Parker, David
PY - 1990/2
Y1 - 1990/2
N2 - 14-Crown-4 derivatives bearing either one or two methoxy, methoxycarbonylmethyl or carbamoylalkyl substituents have been prepared in an attempt to obtain selective ionophores for lithium ions. Complexation with lithium has been monitored by IR and 13C NMR spectroscopy and solvent polymeric membranes have been fabricated and evaluated using the fixed interference method. The highest selectivity for lithium with respect to sodium is observed for a diamide derivative (630:1).
AB - 14-Crown-4 derivatives bearing either one or two methoxy, methoxycarbonylmethyl or carbamoylalkyl substituents have been prepared in an attempt to obtain selective ionophores for lithium ions. Complexation with lithium has been monitored by IR and 13C NMR spectroscopy and solvent polymeric membranes have been fabricated and evaluated using the fixed interference method. The highest selectivity for lithium with respect to sodium is observed for a diamide derivative (630:1).
UR - http://www.scopus.com/inward/record.url?scp=37049067555&partnerID=8YFLogxK
U2 - 10.1039/P29900000321
DO - 10.1039/P29900000321
M3 - Journal article
AN - SCOPUS:37049067555
SN - 1472-779X
SP - 321
EP - 327
JO - Journal of the Chemical Society, Perkin Transactions 2
JF - Journal of the Chemical Society, Perkin Transactions 2
IS - 2
ER -
