CO2加氢合成甲醇催化反应中CO的作用

null 李基涛; null 区泽棠; null 陈明旦; null 张伟德

CO2加氢合成甲醇催化反应中CO的作用

Translated title of the contribution: The role of CO in the synthesis of methanol from the hydrogenation of carbon dioxide

李基涛^*, 区泽棠, 陈明旦, 张伟德

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The effect of adding CO to the raw gases for methanol synthesis from the hydrogenation of carbon dioxide over the CuO/ZnO/Al₂O₃ catalysts has been reported. Small amount of CO in the raw gases can increase the selectivity and yield of methanol by 38% and 25%, respectively. TPD-MS and TPSR-MS results indicate that CO can suppress the adsorption of CO₂ on the sites, which bring about the reverse water-gas shift reaction and hence promote the selectivity of methanol.

Translated title of the contribution	The role of CO in the synthesis of methanol from the hydrogenation of carbon dioxide
Original language	Chinese (Simplified)
Pages (from-to)	926-929
Number of pages	4
Journal	高等学校化学学报
Volume	19
Issue number	6
Publication status	Published - 1998

Scopus Subject Areas

Chemistry(all)

User-Defined Keywords

Co hydrogenation
Effect of CO
Methanol synthesis

Cite this

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title = "CO2加氢合成甲醇催化反应中CO的作用",

abstract = "The effect of adding CO to the raw gases for methanol synthesis from the hydrogenation of carbon dioxide over the CuO/ZnO/Al2O3 catalysts has been reported. Small amount of CO in the raw gases can increase the selectivity and yield of methanol by 38% and 25%, respectively. TPD-MS and TPSR-MS results indicate that CO can suppress the adsorption of CO2 on the sites, which bring about the reverse water-gas shift reaction and hence promote the selectivity of methanol.",

keywords = "Co hydrogenation, Effect of CO, Methanol synthesis",

author = "李基涛 and 区泽棠 and 陈明旦 and 张伟德",

year = "1998",

language = "Chinese (Simplified)",

volume = "19",

pages = "926--929",

journal = "高等学校化学学报",

issn = "0251-0790",

publisher = "Higher Education Press",

number = "6",

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T1 - CO2加氢合成甲醇催化反应中CO的作用

AU - 李基涛, null

AU - 区泽棠, null

AU - 陈明旦, null

AU - 张伟德, null

PY - 1998

Y1 - 1998

N2 - The effect of adding CO to the raw gases for methanol synthesis from the hydrogenation of carbon dioxide over the CuO/ZnO/Al2O3 catalysts has been reported. Small amount of CO in the raw gases can increase the selectivity and yield of methanol by 38% and 25%, respectively. TPD-MS and TPSR-MS results indicate that CO can suppress the adsorption of CO2 on the sites, which bring about the reverse water-gas shift reaction and hence promote the selectivity of methanol.

AB - The effect of adding CO to the raw gases for methanol synthesis from the hydrogenation of carbon dioxide over the CuO/ZnO/Al2O3 catalysts has been reported. Small amount of CO in the raw gases can increase the selectivity and yield of methanol by 38% and 25%, respectively. TPD-MS and TPSR-MS results indicate that CO can suppress the adsorption of CO2 on the sites, which bring about the reverse water-gas shift reaction and hence promote the selectivity of methanol.

KW - Co hydrogenation

KW - Effect of CO

KW - Methanol synthesis

UR - http://www.scopus.com/inward/record.url?scp=2842605744&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:2842605744

VL - 19

SP - 926

EP - 929

JO - 高等学校化学学报

JF - 高等学校化学学报

SN - 0251-0790

IS - 6

ER -

CO2加氢合成甲醇催化反应中CO的作用

Abstract

Scopus Subject Areas

User-Defined Keywords

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