Catalytic asymmetric hydrocyanation of norbornene using chiral biphosphinepalladium complexes

Martin Hodgson; David Parker

doi:10.1016/0022-328X(87)80417-5

Catalytic asymmetric hydrocyanation of norbornene using chiral biphosphinepalladium complexes

Martin Hodgson^*
, David Parker

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

39 Citations (Scopus)

Abstract

Addition of HCN to norbornene is catalysed by Pd(BPPM)₂ or Pd(BINAP)₂ complexes to give the corresponding nitrile in 20 and 40% enantiomeric purity, respectively. Optical yields using Pd(DIOP)₂ are lower than originally surmised.

Original language	English
Pages (from-to)	C27-C30
Journal	Journal of Organometallic Chemistry
Volume	325
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(87)80417-5
Publication status	Published - 12 May 1987

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10.1016/0022-328X(87)80417-5

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@article{30cb66ab93df4384b9d72dab1a535b84,

title = "Catalytic asymmetric hydrocyanation of norbornene using chiral biphosphinepalladium complexes",

abstract = "Addition of HCN to norbornene is catalysed by Pd(BPPM)2 or Pd(BINAP)2 complexes to give the corresponding nitrile in 20 and 40\% enantiomeric purity, respectively. Optical yields using Pd(DIOP)2 are lower than originally surmised.",

author = "Martin Hodgson and David Parker",

note = "Copyright {\textcopyright} 1987 Published by Elsevier B.V.",

year = "1987",

month = may,

day = "12",

doi = "10.1016/0022-328X(87)80417-5",

language = "English",

volume = "325",

pages = "C27--C30",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Catalytic asymmetric hydrocyanation of norbornene using chiral biphosphinepalladium complexes

AU - Hodgson, Martin

AU - Parker, David

PY - 1987/5/12

Y1 - 1987/5/12

N2 - Addition of HCN to norbornene is catalysed by Pd(BPPM)2 or Pd(BINAP)2 complexes to give the corresponding nitrile in 20 and 40% enantiomeric purity, respectively. Optical yields using Pd(DIOP)2 are lower than originally surmised.

AB - Addition of HCN to norbornene is catalysed by Pd(BPPM)2 or Pd(BINAP)2 complexes to give the corresponding nitrile in 20 and 40% enantiomeric purity, respectively. Optical yields using Pd(DIOP)2 are lower than originally surmised.

UR - https://www.scopus.com/pages/publications/0002116591

U2 - 10.1016/0022-328X(87)80417-5

DO - 10.1016/0022-328X(87)80417-5

M3 - Journal article

AN - SCOPUS:0002116591

SN - 0022-328X

VL - 325

SP - C27-C30

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Catalytic asymmetric hydrocyanation of norbornene using chiral biphosphinepalladium complexes

Abstract

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