TY - JOUR
T1 - Brønsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes
AU - Tejo, Ciputra
AU - Tirtorahardjo, Davin
AU - Day, David Philip
AU - Ma, DIk Lung
AU - Leung, Chung Hang
AU - Chan, Philip Wai Hong
N1 - Publisher Copyright:
© 2017 CSIRO.
PY - 2017
Y1 - 2017
N2 - The synthesis of α,α-diacylaziridines and α,α,β-triacylaziridines from reaction of 2-alkyl-substituted-1,3-dicarbonyl compounds and 2-acyl-substituted-1,4-dicarbonyl compounds with arylsulfonyliminoiodinanes (ArSO2N=IPh) under Brønsted base-mediated atmospheric conditions is described. The reaction mechanism is thought to involve the formal oxidation of the substrate followed by aziridination of the ensuing α,β-unsaturated intermediate by the hypervalent iodine(iii) reagent.
AB - The synthesis of α,α-diacylaziridines and α,α,β-triacylaziridines from reaction of 2-alkyl-substituted-1,3-dicarbonyl compounds and 2-acyl-substituted-1,4-dicarbonyl compounds with arylsulfonyliminoiodinanes (ArSO2N=IPh) under Brønsted base-mediated atmospheric conditions is described. The reaction mechanism is thought to involve the formal oxidation of the substrate followed by aziridination of the ensuing α,β-unsaturated intermediate by the hypervalent iodine(iii) reagent.
UR - http://www.scopus.com/inward/record.url?scp=85016821853&partnerID=8YFLogxK
U2 - 10.1071/CH16580
DO - 10.1071/CH16580
M3 - Journal article
AN - SCOPUS:85016821853
SN - 0004-9425
VL - 70
SP - 430
EP - 435
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 4
ER -