Bilayer hollow/spindle-like anatase TiO2 photoanode for high efficiency dye-sensitized solar cells

Guanxi Wang, Xunjin ZHU*, Jiaguo Yu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

58 Citations (Scopus)

Abstract

Derived from a hollow TiO2 nanoparticle (HNP) as underlayer and a TiO2 spindle (SP) as light scattering overlayer, a new bilayer single-crystalline photoanode (HNP/SP) is fabricated for dye-sensitized solar cell (DSSC) application. The prepared bilayer TiO2 photoanode and two comparative HNP/HNP and SP/SP ones are fully characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, UV-vis absorption spectroscopy and N2 adsorption-desorption isotherms. An overall photoelectric conversion efficiency of 8.65% has been achieved for HNP/SP DSSC, which is 25% higher than that of HNP/HNP DSSC, and also far superior to that of SP/SP or conventional P25 DSSC. The improved photovoltaic performance of HNP/SP DSSC is attributed to the synergic effects, i.e. the single-crystalline bilayer structure favoring for rapid interfacial electron transport, the relatively large specific surface area of HNP for effective dye adsorption, and the 1D geometry of single-crystalline TiO2 spindles for direct electron transport pathway and strong light scattering effect.

Original languageEnglish
Pages (from-to)344-351
Number of pages8
JournalJournal of Power Sources
Volume278
DOIs
Publication statusPublished - 15 Mar 2015

Scopus Subject Areas

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

User-Defined Keywords

  • Dye-sensitized solar cells
  • Hollow nanoparticles
  • Single-crystalline bilayer photoanode
  • Spindles
  • Titanium dioxide

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