Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics

David Parker; Rachel S. Dickins; Horst Puschmann; Clare Crossland; Judith A.K. Howard

doi:10.1021/cr010452+

Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics

David Parker^*
, Rachel S. Dickins
, Horst Puschmann
, Clare Crossland
, Judith A.K. Howard

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

877 Citations (Scopus)

Abstract

The complexation chemistry of lanthanide ions in aqueous solutions were shown. Structural aspects of the lanthanide-water bond by a comprehensive analysis of the Cambridge Structural Database (CSD) of all published species in coordination number 9, processing between one and nine bound water molecules, focusing on q=1, 2, and 9 systems. This paper updates aspects of inter- and intramolecular exchange processes, summarizes advances in magnetic resonance spectroscopy, and reviews the developments in the excited-state chemistry of luminescent lanthanide complexes.

Original language	English
Pages (from-to)	1977-2010
Number of pages	34
Journal	Chemical Reviews
Volume	102
Issue number	6
Early online date	21 May 2002
DOIs	https://doi.org/10.1021/cr010452+
Publication status	Published - 1 Jun 2002

Access to Document

10.1021/cr010452+

Cite this

@article{09e0d0a4e92f4fb297492f3f87f4d953,

title = "Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics",

abstract = "The complexation chemistry of lanthanide ions in aqueous solutions were shown. Structural aspects of the lanthanide-water bond by a comprehensive analysis of the Cambridge Structural Database (CSD) of all published species in coordination number 9, processing between one and nine bound water molecules, focusing on q=1, 2, and 9 systems. This paper updates aspects of inter- and intramolecular exchange processes, summarizes advances in magnetic resonance spectroscopy, and reviews the developments in the excited-state chemistry of luminescent lanthanide complexes.",

author = "David Parker and Dickins, \{Rachel S.\} and Horst Puschmann and Clare Crossland and Howard, \{Judith A.K.\}",

note = "It is a pleasure to thank Professors Mauro Botta, Lorenzo di Bari, and Ivano Bertini for the data in Figures 12, 9, and 16 as well as those cited below, especially the current and past co-workers and collaborators for their inspiration in some of the recent work described. Support from (JAKH-Senior Advanced Fellowship; HP-postdoctoral fellowship) the Royal Society (R.S.D.), and the EC COST Action D-18 (Lanthanide Chemistry for Diagnosis and Therapy) is also gratefully acknowledged. Publisher Copyright: {\textcopyright} 2002 American Chemical Society",

year = "2002",

month = jun,

day = "1",

doi = "10.1021/cr010452+",

language = "English",

volume = "102",

pages = "1977--2010",

journal = "Chemical Reviews",

issn = "0009-2665",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Being excited by lanthanide coordination complexes

T2 - Aqua species, chirality, excited-state chemistry, and exchange dynamics

AU - Parker, David

AU - Dickins, Rachel S.

AU - Puschmann, Horst

AU - Crossland, Clare

AU - Howard, Judith A.K.

N1 - It is a pleasure to thank Professors Mauro Botta, Lorenzo di Bari, and Ivano Bertini for the data in Figures 12, 9, and 16 as well as those cited below, especially the current and past co-workers and collaborators for their inspiration in some of the recent work described. Support from (JAKH-Senior Advanced Fellowship; HP-postdoctoral fellowship) the Royal Society (R.S.D.), and the EC COST Action D-18 (Lanthanide Chemistry for Diagnosis and Therapy) is also gratefully acknowledged. Publisher Copyright: © 2002 American Chemical Society

PY - 2002/6/1

Y1 - 2002/6/1

N2 - The complexation chemistry of lanthanide ions in aqueous solutions were shown. Structural aspects of the lanthanide-water bond by a comprehensive analysis of the Cambridge Structural Database (CSD) of all published species in coordination number 9, processing between one and nine bound water molecules, focusing on q=1, 2, and 9 systems. This paper updates aspects of inter- and intramolecular exchange processes, summarizes advances in magnetic resonance spectroscopy, and reviews the developments in the excited-state chemistry of luminescent lanthanide complexes.

AB - The complexation chemistry of lanthanide ions in aqueous solutions were shown. Structural aspects of the lanthanide-water bond by a comprehensive analysis of the Cambridge Structural Database (CSD) of all published species in coordination number 9, processing between one and nine bound water molecules, focusing on q=1, 2, and 9 systems. This paper updates aspects of inter- and intramolecular exchange processes, summarizes advances in magnetic resonance spectroscopy, and reviews the developments in the excited-state chemistry of luminescent lanthanide complexes.

UR - https://www.scopus.com/pages/publications/0036625419

U2 - 10.1021/cr010452+

DO - 10.1021/cr010452+

M3 - Journal article

AN - SCOPUS:0036625419

SN - 0009-2665

VL - 102

SP - 1977

EP - 2010

JO - Chemical Reviews

JF - Chemical Reviews

IS - 6

ER -

Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics

Abstract

Access to Document

Other files and links

Fingerprint

Cite this