Azaxanthones and azathioxanthones are effective sensitisers for europium and terbium luminescence

Paul Atkinson, Karen S. Findlay, Filip Kielar, Robert Pal, David Parker*, Robert A. Poole, Horst Puschmann, Siobhan L. Richardson, Philip A. Stenson, Amber L. Thompson, Junhau Yu

*Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

68 Citations (Scopus)

Abstract

Several azaxanthone and azathioxanthone sensitising chromophores have been incorporated into macrocyclic ligands and form well-defined Eu and Tb complexes in polar media. Excitation of the heterocyclic chromophore in the range 330 to 382 nm leads to modest amounts of aromatic fluorescence and relatively efficient metal-based luminescence, with absolute metal-based quantum yields of up to 24% in aqueous media.
Original languageEnglish
Pages (from-to)1707-1722
Number of pages16
JournalOrganic and Biomolecular Chemistry
Volume4
Issue number9
DOIs
Publication statusPublished - 23 Mar 2006

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