Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex

Lu Yu; Yongyun Zhou; Xin Xu; Sifeng Li; Jianbin Xu; Baomin Fan; Chengyuan Lin; Zhaoxiang BIAN; Albert S C Chan

doi:10.1016/j.tetlet.2014.09.089

Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex

Lu Yu, Yongyun Zhou, Xin Xu, Sifeng Li, Jianbin Xu, Baomin Fan^*, Chengyuan Lin, Zhaoxiang BIAN, Albert S C Chan

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › peer-review

15 Citations (Scopus)

Abstract

As an efficient catalyst, the [Ir(COD)Cl]₂/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72-98%) with good enantioselectivities (80-90% ee).

Original language	English
Pages (from-to)	6315-6318
Number of pages	4
Journal	Tetrahedron Letters
Volume	55
Issue number	46
DOIs	https://doi.org/10.1016/j.tetlet.2014.09.089
Publication status	Published - 12 Nov 2014

Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

User-Defined Keywords

ARO reaction (S)-NMDPP Amines
Oxabenzonorbornadienes

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10.1016/j.tetlet.2014.09.089

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@article{c30f5850c6d54fdfb5f73d3fbb232f82,

title = "Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex",

abstract = "As an efficient catalyst, the [Ir(COD)Cl]2/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72-98%) with good enantioselectivities (80-90% ee).",

keywords = "ARO reaction (S)-NMDPP Amines, Oxabenzonorbornadienes",

author = "Lu Yu and Yongyun Zhou and Xin Xu and Sifeng Li and Jianbin Xu and Baomin Fan and Chengyuan Lin and Zhaoxiang BIAN and Chan, {Albert S C}",

note = "Funding Information: We thank the National Natural Science Foundation of China – China ( 21362043 , 21162040 , 21302162 ), the Government of Yunnan Province ( 2012FB170 ), and the State Key Laboratory of Elemento-organic Chemistry, Nankai University , ( 201302 ) for financial support. ",

year = "2014",

month = nov,

day = "12",

doi = "10.1016/j.tetlet.2014.09.089",

language = "English",

volume = "55",

pages = "6315--6318",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "46",

}

TY - JOUR

T1 - Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex

AU - Yu, Lu

AU - Zhou, Yongyun

AU - Xu, Xin

AU - Li, Sifeng

AU - Xu, Jianbin

AU - Fan, Baomin

AU - Lin, Chengyuan

AU - BIAN, Zhaoxiang

AU - Chan, Albert S C

N1 - Funding Information: We thank the National Natural Science Foundation of China – China ( 21362043 , 21162040 , 21302162 ), the Government of Yunnan Province ( 2012FB170 ), and the State Key Laboratory of Elemento-organic Chemistry, Nankai University , ( 201302 ) for financial support.

PY - 2014/11/12

Y1 - 2014/11/12

N2 - As an efficient catalyst, the [Ir(COD)Cl]2/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72-98%) with good enantioselectivities (80-90% ee).

AB - As an efficient catalyst, the [Ir(COD)Cl]2/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72-98%) with good enantioselectivities (80-90% ee).

KW - ARO reaction (S)-NMDPP Amines

KW - Oxabenzonorbornadienes

UR - http://www.scopus.com/inward/record.url?scp=84908260379&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2014.09.089

DO - 10.1016/j.tetlet.2014.09.089

M3 - Journal article

AN - SCOPUS:84908260379

SN - 0040-4039

VL - 55

SP - 6315

EP - 6318

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex

Abstract

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