Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex

Lu Yu, Yongyun Zhou, Xin Xu, Sifeng Li, Jianbin Xu, Baomin Fan*, Chengyuan Lin, Zhaoxiang BIAN, Albert S C Chan

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

As an efficient catalyst, the [Ir(COD)Cl]2/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72-98%) with good enantioselectivities (80-90% ee).

Original languageEnglish
Pages (from-to)6315-6318
Number of pages4
JournalTetrahedron Letters
Volume55
Issue number46
DOIs
Publication statusPublished - 12 Nov 2014

Scopus Subject Areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

User-Defined Keywords

  • ARO reaction (S)-NMDPP Amines
  • Oxabenzonorbornadienes

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