Assembly of organosilver (I) networks with multinuclear supramolecular synthons containing all-carbon and carbon-rich anionic ligands

Sam C K Hau; Ting Hu; Dennis Y. S. Tam; Thomas C. W. Mak

doi:10.7503/cjcu20150601

Assembly of organosilver (I) networks with multinuclear supramolecular synthons containing all-carbon and carbon-rich anionic ligands

Sam C K Hau, Ting Hu, Dennis Y. S. Tam, Thomas C. W. Mak^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

3 Citations (Scopus)

Abstract

This review summarizes recent advances conducted by our group on related silver complexes of (a) all-carbon ligands C₆^2- and C₈^2-, (b) 1,5-hexadiyne-1,6-diide C₆H₄^2-, (c) ethynediide C₂^2- and ethynide R-C₂^- assembled with phosphonic acids, (d) aryl, alicyclic and heteroaromatic ethynides, and (e) ethynides that are stabilized by different types of silver⋯carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.

Original language	English
Pages (from-to)	2115-2133
Number of pages	19
Journal	Chemical Journal of Chinese Universities
Volume	36
Issue number	11
DOIs	https://doi.org/10.7503/cjcu20150601
Publication status	Published - 1 Nov 2015

User-Defined Keywords

All-carbon ligand
Argentophilicity
Carbon-rich ligand
Ethynide
Organosilver (I) network
Supramolecular synthon

Access to Document

10.7503/cjcu20150601

Cite this

@article{677b989e489648889b672909eab42333,

title = "Assembly of organosilver (I) networks with multinuclear supramolecular synthons containing all-carbon and carbon-rich anionic ligands",

abstract = "This review summarizes recent advances conducted by our group on related silver complexes of (a) all-carbon ligands C62- and C82-, (b) 1,5-hexadiyne-1,6-diide C6H42-, (c) ethynediide C22- and ethynide R-C2- assembled with phosphonic acids, (d) aryl, alicyclic and heteroaromatic ethynides, and (e) ethynides that are stabilized by different types of silver⋯carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.",

keywords = "All-carbon ligand, Argentophilicity, Carbon-rich ligand, Ethynide, Organosilver (I) network, Supramolecular synthon",

author = "Hau, {Sam C K} and Ting Hu and Tam, {Dennis Y. S.} and Mak, {Thomas C. W.}",

note = "This paper is supported by the Project of the Hong Kong Research Grants Council (Nos. CUHK 402408, 402710) and the Wei Lun Foundation.",

year = "2015",

month = nov,

day = "1",

doi = "10.7503/cjcu20150601",

language = "English",

volume = "36",

pages = "2115--2133",

journal = "Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "11",

}

TY - JOUR

T1 - Assembly of organosilver (I) networks with multinuclear supramolecular synthons containing all-carbon and carbon-rich anionic ligands

AU - Hau, Sam C K

AU - Hu, Ting

AU - Tam, Dennis Y. S.

AU - Mak, Thomas C. W.

N1 - This paper is supported by the Project of the Hong Kong Research Grants Council (Nos. CUHK 402408, 402710) and the Wei Lun Foundation.

PY - 2015/11/1

Y1 - 2015/11/1

N2 - This review summarizes recent advances conducted by our group on related silver complexes of (a) all-carbon ligands C62- and C82-, (b) 1,5-hexadiyne-1,6-diide C6H42-, (c) ethynediide C22- and ethynide R-C2- assembled with phosphonic acids, (d) aryl, alicyclic and heteroaromatic ethynides, and (e) ethynides that are stabilized by different types of silver⋯carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.

AB - This review summarizes recent advances conducted by our group on related silver complexes of (a) all-carbon ligands C62- and C82-, (b) 1,5-hexadiyne-1,6-diide C6H42-, (c) ethynediide C22- and ethynide R-C2- assembled with phosphonic acids, (d) aryl, alicyclic and heteroaromatic ethynides, and (e) ethynides that are stabilized by different types of silver⋯carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.

KW - All-carbon ligand

KW - Argentophilicity

KW - Carbon-rich ligand

KW - Ethynide

KW - Organosilver (I) network

KW - Supramolecular synthon

UR - http://www.scopus.com/inward/record.url?scp=84949429350&partnerID=8YFLogxK

U2 - 10.7503/cjcu20150601

DO - 10.7503/cjcu20150601

M3 - Journal article

AN - SCOPUS:84949429350

SN - 0251-0790

VL - 36

SP - 2115

EP - 2133

JO - Chemical Journal of Chinese Universities

JF - Chemical Journal of Chinese Universities

IS - 11

ER -

Assembly of organosilver (I) networks with multinuclear supramolecular synthons containing all-carbon and carbon-rich anionic ligands

Abstract

User-Defined Keywords

Access to Document

Other files and links

Fingerprint

Cite this