Aqueous solutions of uranium(VI) as studied by time-resolved emission spectroscopy: A round-robin test

Isabelle Billard; Eric Ansoborlo; Kathleen Apperson; Sylvie Arpigny; M. Emilia Azenha; David Birch; Pascal Bros; Hugh D. Burrows; Gregory Choppin; Laurent Couston; Veronique Dubois; Thomas Fanghänel; Gerhard Geipel; Solange Hubert; Jae I. Kim; Takaumi Kimura; Reinhardt Klenze; Andreas Kronenberg; Michael Kumke; Gerard Lagarde; Gerard Lamarque; Stefan Lis; Charles Madic; Gunther Meinrath; Christophe Moulin; Ryuji Nagaishi; David Parker; Gabriel Plancque; Franz Scherbaum; Eric Simoni; Sergei Sinkov; Carole Viallesoubranne

doi:10.1366/000370203322259002

Aqueous solutions of uranium(VI) as studied by time-resolved emission spectroscopy: A round-robin test

Isabelle Billard^*, Eric Ansoborlo, Kathleen Apperson, Sylvie Arpigny, M. Emilia Azenha, David Birch, Pascal Bros, Hugh D. Burrows, Gregory Choppin, Laurent Couston, Veronique Dubois, Thomas Fanghänel, Gerhard Geipel, Solange Hubert, Jae I. Kim, Takaumi Kimura, Reinhardt Klenze, Andreas Kronenberg, Michael Kumke, Gerard LagardeGerard Lamarque, Stefan Lis, Charles Madic, Gunther Meinrath, Christophe Moulin, Ryuji Nagaishi, David Parker, Gabriel Plancque, Franz Scherbaum, Eric Simoni, Sergei Sinkov, Carole Viallesoubranne

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

44 Citations (Scopus)

Abstract

Results of an inter-laboratory round-robin study of the application of time-resolved emission spectroscopy (TRES) to the speclation of uranium(VI) in aqueous media are presented. The round-robin study involved 13 independent laboratories, using various instrumentation and data analysis methods. Samples were prepared based on appropriate speciation diagrams and, in general, were found to be chemically stable for at least six months. Four different types of aqueous uranyl solutions were studied: (1) acidic medium where UO ₂²⁺_aq is the single emitting species, (2) uranyl in the presence of fluoride ions, (3) uranyl in the presence of sulfate ions, and (4) uranyl in aqueous solutions at different pH, promoting the formation of hydrolyzed species. Results between the laboratories are compared in terms of the number of decay components, luminescence lifetimes, and spectral band positions. The successes and limitations of TRES in uranyl analysis and speciation in aqueous solutions are discussed.

Original language	English
Pages (from-to)	1027-1038
Number of pages	12
Journal	Applied Spectroscopy
Volume	57
Issue number	8
DOIs	https://doi.org/10.1366/000370203322259002
Publication status	Published - Aug 2003

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Intercomparison
Speciation
Uranium(VI)

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Billard, I., Ansoborlo, E., Apperson, K., Arpigny, S., Azenha, M. E., Birch, D., Bros, P., Burrows, H. D., Choppin, G., Couston, L., Dubois, V., Fanghänel, T., Geipel, G., Hubert, S., Kim, J. I., Kimura, T., Klenze, R., Kronenberg, A., Kumke, M., ... Viallesoubranne, C. (2003). Aqueous solutions of uranium(VI) as studied by time-resolved emission spectroscopy: A round-robin test. Applied Spectroscopy, 57(8), 1027-1038. https://doi.org/10.1366/000370203322259002

@article{cdf6b7afc2254697bfd8aa422903ea1e,

title = "Aqueous solutions of uranium(VI) as studied by time-resolved emission spectroscopy: A round-robin test",

abstract = "Results of an inter-laboratory round-robin study of the application of time-resolved emission spectroscopy (TRES) to the speclation of uranium(VI) in aqueous media are presented. The round-robin study involved 13 independent laboratories, using various instrumentation and data analysis methods. Samples were prepared based on appropriate speciation diagrams and, in general, were found to be chemically stable for at least six months. Four different types of aqueous uranyl solutions were studied: (1) acidic medium where UO 22+aq is the single emitting species, (2) uranyl in the presence of fluoride ions, (3) uranyl in the presence of sulfate ions, and (4) uranyl in aqueous solutions at different pH, promoting the formation of hydrolyzed species. Results between the laboratories are compared in terms of the number of decay components, luminescence lifetimes, and spectral band positions. The successes and limitations of TRES in uranyl analysis and speciation in aqueous solutions are discussed.",

keywords = "Intercomparison, Speciation, Uranium(VI)",

author = "Isabelle Billard and Eric Ansoborlo and Kathleen Apperson and Sylvie Arpigny and Azenha, {M. Emilia} and David Birch and Pascal Bros and Burrows, {Hugh D.} and Gregory Choppin and Laurent Couston and Veronique Dubois and Thomas Fangh{\"a}nel and Gerhard Geipel and Solange Hubert and Kim, {Jae I.} and Takaumi Kimura and Reinhardt Klenze and Andreas Kronenberg and Michael Kumke and Gerard Lagarde and Gerard Lamarque and Stefan Lis and Charles Madic and Gunther Meinrath and Christophe Moulin and Ryuji Nagaishi and David Parker and Gabriel Plancque and Franz Scherbaum and Eric Simoni and Sergei Sinkov and Carole Viallesoubranne",

year = "2003",

month = aug,

doi = "10.1366/000370203322259002",

language = "English",

volume = "57",

pages = "1027--1038",

journal = "Applied Spectroscopy",

issn = "0003-7028",

publisher = "SAGE Publications Inc.",

number = "8",

}

Billard, I, Ansoborlo, E, Apperson, K, Arpigny, S, Azenha, ME, Birch, D, Bros, P, Burrows, HD, Choppin, G, Couston, L, Dubois, V, Fanghänel, T, Geipel, G, Hubert, S, Kim, JI, Kimura, T, Klenze, R, Kronenberg, A, Kumke, M, Lagarde, G, Lamarque, G, Lis, S, Madic, C, Meinrath, G, Moulin, C, Nagaishi, R, Parker, D, Plancque, G, Scherbaum, F, Simoni, E, Sinkov, S & Viallesoubranne, C 2003, 'Aqueous solutions of uranium(VI) as studied by time-resolved emission spectroscopy: A round-robin test', Applied Spectroscopy, vol. 57, no. 8, pp. 1027-1038. https://doi.org/10.1366/000370203322259002

TY - JOUR

T1 - Aqueous solutions of uranium(VI) as studied by time-resolved emission spectroscopy

T2 - A round-robin test

AU - Billard, Isabelle

AU - Ansoborlo, Eric

AU - Apperson, Kathleen

AU - Arpigny, Sylvie

AU - Azenha, M. Emilia

AU - Birch, David

AU - Bros, Pascal

AU - Burrows, Hugh D.

AU - Choppin, Gregory

AU - Couston, Laurent

AU - Dubois, Veronique

AU - Fanghänel, Thomas

AU - Geipel, Gerhard

AU - Hubert, Solange

AU - Kim, Jae I.

AU - Kimura, Takaumi

AU - Klenze, Reinhardt

AU - Kronenberg, Andreas

AU - Kumke, Michael

AU - Lagarde, Gerard

AU - Lamarque, Gerard

AU - Lis, Stefan

AU - Madic, Charles

AU - Meinrath, Gunther

AU - Moulin, Christophe

AU - Nagaishi, Ryuji

AU - Parker, David

AU - Plancque, Gabriel

AU - Scherbaum, Franz

AU - Simoni, Eric

AU - Sinkov, Sergei

AU - Viallesoubranne, Carole

PY - 2003/8

Y1 - 2003/8

N2 - Results of an inter-laboratory round-robin study of the application of time-resolved emission spectroscopy (TRES) to the speclation of uranium(VI) in aqueous media are presented. The round-robin study involved 13 independent laboratories, using various instrumentation and data analysis methods. Samples were prepared based on appropriate speciation diagrams and, in general, were found to be chemically stable for at least six months. Four different types of aqueous uranyl solutions were studied: (1) acidic medium where UO 22+aq is the single emitting species, (2) uranyl in the presence of fluoride ions, (3) uranyl in the presence of sulfate ions, and (4) uranyl in aqueous solutions at different pH, promoting the formation of hydrolyzed species. Results between the laboratories are compared in terms of the number of decay components, luminescence lifetimes, and spectral band positions. The successes and limitations of TRES in uranyl analysis and speciation in aqueous solutions are discussed.

AB - Results of an inter-laboratory round-robin study of the application of time-resolved emission spectroscopy (TRES) to the speclation of uranium(VI) in aqueous media are presented. The round-robin study involved 13 independent laboratories, using various instrumentation and data analysis methods. Samples were prepared based on appropriate speciation diagrams and, in general, were found to be chemically stable for at least six months. Four different types of aqueous uranyl solutions were studied: (1) acidic medium where UO 22+aq is the single emitting species, (2) uranyl in the presence of fluoride ions, (3) uranyl in the presence of sulfate ions, and (4) uranyl in aqueous solutions at different pH, promoting the formation of hydrolyzed species. Results between the laboratories are compared in terms of the number of decay components, luminescence lifetimes, and spectral band positions. The successes and limitations of TRES in uranyl analysis and speciation in aqueous solutions are discussed.

KW - Intercomparison

KW - Speciation

KW - Uranium(VI)

UR - http://www.scopus.com/inward/record.url?scp=0041878481&partnerID=8YFLogxK

U2 - 10.1366/000370203322259002

DO - 10.1366/000370203322259002

M3 - Journal article

C2 - 14661847

AN - SCOPUS:0041878481

SN - 0003-7028

VL - 57

SP - 1027

EP - 1038

JO - Applied Spectroscopy

JF - Applied Spectroscopy

IS - 8

ER -

Aqueous solutions of uranium(VI) as studied by time-resolved emission spectroscopy: A round-robin test

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