An efficient oxidative cross-coupling reaction between C-H and N-H Bonds; A transition-metal-free protocol at room temperature

Yinuo Wu; Fuk Yee Kwong; Pengfei Li; Alberts C. Chan

doi:10.1055/s-0033-1339447

An efficient oxidative cross-coupling reaction between C-H and N-H Bonds; A transition-metal-free protocol at room temperature

Yinuo Wu
, Fuk Yee Kwong
, Pengfei Li^*
, Alberts C. Chan

^*Corresponding author for this work

Research output: Contribution to journal › Letter › peer-review

22 Citations (Scopus)

Abstract

A transition-metal-free oxidative coupling of allylic C-H and heterocyclic/aromatic N-H bonds was performed under mild conditions. Promoted by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), up to 99% yield could be achieved.

Original language	English
Pages (from-to)	2009-2013
Number of pages	5
Journal	Synlett
Volume	24
Issue number	15
Early online date	3 Aug 2013
DOIs	https://doi.org/10.1055/s-0033-1339447
Publication status	Published - Sept 2013

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 9 Industry, Innovation, and Infrastructure

User-Defined Keywords

amination
C-H activation
cross-coupling
metal-free
oxidative coupling

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10.1055/s-0033-1339447

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abstract = "A transition-metal-free oxidative coupling of allylic C-H and heterocyclic/aromatic N-H bonds was performed under mild conditions. Promoted by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), up to 99\% yield could be achieved.",

keywords = "amination, C-H activation, cross-coupling, metal-free, oxidative coupling",

author = "Yinuo Wu and Kwong, \{Fuk Yee\} and Pengfei Li and Chan, \{Alberts C.\}",

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AU - Wu, Yinuo

AU - Kwong, Fuk Yee

AU - Li, Pengfei

AU - Chan, Alberts C.

N1 - Publisher copyright: © Georg Thieme Verlag Stuttgart · New York

PY - 2013/9

Y1 - 2013/9

N2 - A transition-metal-free oxidative coupling of allylic C-H and heterocyclic/aromatic N-H bonds was performed under mild conditions. Promoted by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), up to 99% yield could be achieved.

AB - A transition-metal-free oxidative coupling of allylic C-H and heterocyclic/aromatic N-H bonds was performed under mild conditions. Promoted by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), up to 99% yield could be achieved.

KW - amination

KW - C-H activation

KW - cross-coupling

KW - metal-free

KW - oxidative coupling

UR - https://www.scopus.com/pages/publications/84881090661

U2 - 10.1055/s-0033-1339447

DO - 10.1055/s-0033-1339447

M3 - Letter

AN - SCOPUS:84881090661

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JO - Synlett

JF - Synlett

IS - 15

ER -

An efficient oxidative cross-coupling reaction between C-H and N-H Bonds; A transition-metal-free protocol at room temperature

Abstract

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