@article{1b7ca5d2987b425d9efd7382082843a6,
title = "An approach towards the construction of the tetracyclic skeleton of palhinine alkaloids",
abstract = "A concise synthesis of the tetracyclic skeleton of palhinine alkaloids is described. The approach features a bifunctional Lewis acid promoted Diels-Alder/carbocyclization cascade for the rapid construction of the isotwistane (tricyclo[4.3.1.03,7]decane) core. This key reaction is highly diastereoselective and could be carried out on gram scale. The cyclization product already possesses the completed ring system of palhinine alkaloids and could potentially be further functionalized to palhinine A.",
author = "Congcong Han and Yang Chen and Ching, {Yin Cheung} and Lee, {Chi Sing} and Shuzhong He",
note = "Funding Information: We thank the National Natural Science Foundation of China (Grant No. 21861010, 21562011, and 21871017), the Guizhou Provincial Natural Science Foundation (Qian Ke He platform talents [2018]5781), the Case Base Construction Project for Guizhou Graduate Education (KCALK2017012), Guizhou University (No. [2017]32, [2014]36) and Baptist University of Hong Kong (RC-SGT2/18-19/SCI/005 and RC-ICRS-18-19-01A) for their financial support.",
year = "2020",
month = aug,
day = "21",
doi = "10.1039/d0qo00554a",
language = "English",
volume = "7",
pages = "2243--2246",
journal = "Organic Chemistry Frontiers",
issn = "2052-4110",
publisher = "Royal Society of Chemistry",
number = "16",
}