Air-stable Organobismuth(V) Bisperfluorooctanesulfonate as an Efficient Catalyst for the Synthesis of N-Containing Compounds

Penghui Wang; Jinying Wang; Chak Tong Au; Renhua Qiu; Xinhua Xu; Shuang Feng Yin

doi:10.1002/adsc.201500998

Air-stable Organobismuth(V) Bisperfluorooctanesulfonate as an Efficient Catalyst for the Synthesis of N-Containing Compounds

Penghui Wang, Jinying Wang, Chak Tong Au, Renhua Qiu, Xinhua Xu, Shuang Feng Yin

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

27 Citations (Scopus)

Abstract

Triphenyl bismuth bisperfluorooctanesulfonate is an air- and water-stable Lewis acid. It exhibits high catalytic efficiency for the synthesis of nitrogen heterocycles such as diindolylmethane derivatives, dihydropyrimidinones, dihydropyridines and 1,2-disubstitued benzimidazoles under mild condition. Furthermore, it can be reused without loss of activity in a test of five cycles.This catalytic system affords a simple and efficient way for the synthesis of N-containing compounds.

Original language	English
Pages (from-to)	1302-1308
Number of pages	7
Journal	Advanced Synthesis & Catalysis
Volume	358
Issue number	8
DOIs	https://doi.org/10.1002/adsc.201500998
Publication status	Published - 14 Apr 2016

Scopus Subject Areas

Catalysis
Organic Chemistry

User-Defined Keywords

Lewis acids
nitrogen heterocycles
perfluorooctanesulfonate
triphenyl bismuth

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10.1002/adsc.201500998

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title = "Air-stable Organobismuth(V) Bisperfluorooctanesulfonate as an Efficient Catalyst for the Synthesis of N-Containing Compounds",

abstract = "Triphenyl bismuth bisperfluorooctanesulfonate is an air- and water-stable Lewis acid. It exhibits high catalytic efficiency for the synthesis of nitrogen heterocycles such as diindolylmethane derivatives, dihydropyrimidinones, dihydropyridines and 1,2-disubstitued benzimidazoles under mild condition. Furthermore, it can be reused without loss of activity in a test of five cycles.This catalytic system affords a simple and efficient way for the synthesis of N-containing compounds.",

keywords = "Lewis acids, nitrogen heterocycles, perfluorooctanesulfonate, triphenyl bismuth",

author = "Penghui Wang and Jinying Wang and Au, {Chak Tong} and Renhua Qiu and Xinhua Xu and Yin, {Shuang Feng}",

note = "Funding Information: The authors thank the Natural Science Foundation of China (Nos. 21373003 and 21273068) and the Fundamental Research Funds for the Central Universities for financial support. R.Q. thanks Prof. Junzo Otera and Prof. Akihiro Orita (Okayama University of Science), Prof. Nobuaki Kambe (Osaka University), and Prof. Li-biao Han (AIST, Tsukuba) for helpful discussions. C.T. Au thanks Hunan University for an adjunct professorship.",

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doi = "10.1002/adsc.201500998",

language = "English",

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pages = "1302--1308",

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TY - JOUR

T1 - Air-stable Organobismuth(V) Bisperfluorooctanesulfonate as an Efficient Catalyst for the Synthesis of N-Containing Compounds

AU - Wang, Penghui

AU - Wang, Jinying

AU - Au, Chak Tong

AU - Qiu, Renhua

AU - Xu, Xinhua

AU - Yin, Shuang Feng

N1 - Funding Information: The authors thank the Natural Science Foundation of China (Nos. 21373003 and 21273068) and the Fundamental Research Funds for the Central Universities for financial support. R.Q. thanks Prof. Junzo Otera and Prof. Akihiro Orita (Okayama University of Science), Prof. Nobuaki Kambe (Osaka University), and Prof. Li-biao Han (AIST, Tsukuba) for helpful discussions. C.T. Au thanks Hunan University for an adjunct professorship.

PY - 2016/4/14

Y1 - 2016/4/14

N2 - Triphenyl bismuth bisperfluorooctanesulfonate is an air- and water-stable Lewis acid. It exhibits high catalytic efficiency for the synthesis of nitrogen heterocycles such as diindolylmethane derivatives, dihydropyrimidinones, dihydropyridines and 1,2-disubstitued benzimidazoles under mild condition. Furthermore, it can be reused without loss of activity in a test of five cycles.This catalytic system affords a simple and efficient way for the synthesis of N-containing compounds.

AB - Triphenyl bismuth bisperfluorooctanesulfonate is an air- and water-stable Lewis acid. It exhibits high catalytic efficiency for the synthesis of nitrogen heterocycles such as diindolylmethane derivatives, dihydropyrimidinones, dihydropyridines and 1,2-disubstitued benzimidazoles under mild condition. Furthermore, it can be reused without loss of activity in a test of five cycles.This catalytic system affords a simple and efficient way for the synthesis of N-containing compounds.

KW - Lewis acids

KW - nitrogen heterocycles

KW - perfluorooctanesulfonate

KW - triphenyl bismuth

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DO - 10.1002/adsc.201500998

M3 - Journal article

AN - SCOPUS:84961285328

SN - 1615-4150

VL - 358

SP - 1302

EP - 1308

JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

IS - 8

ER -

Air-stable Organobismuth(V) Bisperfluorooctanesulfonate as an Efficient Catalyst for the Synthesis of N-Containing Compounds

Abstract

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