Advances in transition metal catalyzed selective B–H functionalization of o-carboranes

Jie Zhang; Zuowei Xie

doi:10.1016/bs.acat.2022.04.003

Advances in transition metal catalyzed selective B–H functionalization of o-carboranes

Jie Zhang
, Zuowei Xie^*

^*Corresponding author for this work

Department of Chemistry

Research output: Chapter in book/report/conference proceeding › Chapter › peer-review

17 Citations (Scopus)

Abstract

Carboranes are a class of carbon-boron molecular clusters, possessing extraordinary characteristics including three-dimensional aromaticity conjugated by σ-bonds, icosahedral geometry and inherent robustness. They are finding a variety of applications in medicine, materials and coordination/organometallic chemistry, and more. Thus, selective functionalization of o-carboranes has attracted enormous research interests, particularly in regio- and enantio-selective cage BH derivatization among ten chemically similar BH vertices in o-carboranes. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization. This review summarizes recent advances in this research realm.

Original language	English
Title of host publication	Advances in the Synthesis and Catalytic Applications of Boron Clusters
Subtitle of host publication	A Tribute to the Works of Professor Francesc Teixidor and Professor Clara Viñas
Editors	Montserrat Diéguez, Rosario Núñez
Publisher	Academic Press Inc.
Chapter	3
Pages	91-167
Number of pages	77
ISBN (Print)	9780323988315
DOIs	https://doi.org/10.1016/bs.acat.2022.04.003
Publication status	Published - 26 Sept 2022

Publication series

Name	Advances in Catalysis
Volume	71
ISSN (Print)	0360-0564

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 9 Industry, Innovation, and Infrastructure

User-Defined Keywords

Asymmetric catalysis
B-H functionalization
Base-metal catalysis
Boron
Carborane
Cascade reaction
Electrochemistry
Transition-metal catalysis

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10.1016/bs.acat.2022.04.003

Cite this

Zhang, J., & Xie, Z. (2022). Advances in transition metal catalyzed selective B–H functionalization of o-carboranes. In M. Diéguez, & R. Núñez (Eds.), Advances in the Synthesis and Catalytic Applications of Boron Clusters: A Tribute to the Works of Professor Francesc Teixidor and Professor Clara Viñas (pp. 91-167). (Advances in Catalysis; Vol. 71). Academic Press Inc.. https://doi.org/10.1016/bs.acat.2022.04.003

Zhang, Jie ; Xie, Zuowei. / Advances in transition metal catalyzed selective B–H functionalization of o-carboranes. Advances in the Synthesis and Catalytic Applications of Boron Clusters: A Tribute to the Works of Professor Francesc Teixidor and Professor Clara Viñas. editor / Montserrat Diéguez ; Rosario Núñez. Academic Press Inc., 2022. pp. 91-167 (Advances in Catalysis).

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title = "Advances in transition metal catalyzed selective B–H functionalization of o-carboranes",

abstract = "Carboranes are a class of carbon-boron molecular clusters, possessing extraordinary characteristics including three-dimensional aromaticity conjugated by σ-bonds, icosahedral geometry and inherent robustness. They are finding a variety of applications in medicine, materials and coordination/organometallic chemistry, and more. Thus, selective functionalization of o-carboranes has attracted enormous research interests, particularly in regio- and enantio-selective cage BH derivatization among ten chemically similar BH vertices in o-carboranes. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization. This review summarizes recent advances in this research realm.",

keywords = "Asymmetric catalysis, B-H functionalization, Base-metal catalysis, Boron, Carborane, Cascade reaction, Electrochemistry, Transition-metal catalysis",

author = "Jie Zhang and Zuowei Xie",

note = "Financial supports from Research Grants Council of Hong Kong Special Administration Region (Project Nos. 14305918, 14306519, 14305420 and SRFS2021-4S05) are gratefully acknowledged. Publisher Copyright: {\textcopyright} 2022 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.",

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Zhang, J & Xie, Z 2022, Advances in transition metal catalyzed selective B–H functionalization of o-carboranes. in M Diéguez & R Núñez (eds), Advances in the Synthesis and Catalytic Applications of Boron Clusters: A Tribute to the Works of Professor Francesc Teixidor and Professor Clara Viñas. Advances in Catalysis, vol. 71, Academic Press Inc., pp. 91-167. https://doi.org/10.1016/bs.acat.2022.04.003

Advances in transition metal catalyzed selective B–H functionalization of o-carboranes. / Zhang, Jie; Xie, Zuowei.
Advances in the Synthesis and Catalytic Applications of Boron Clusters: A Tribute to the Works of Professor Francesc Teixidor and Professor Clara Viñas. ed. / Montserrat Diéguez; Rosario Núñez. Academic Press Inc., 2022. p. 91-167 (Advances in Catalysis; Vol. 71).

Research output: Chapter in book/report/conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Advances in transition metal catalyzed selective B–H functionalization of o-carboranes

AU - Zhang, Jie

AU - Xie, Zuowei

N1 - Financial supports from Research Grants Council of Hong Kong Special Administration Region (Project Nos. 14305918, 14306519, 14305420 and SRFS2021-4S05) are gratefully acknowledged. Publisher Copyright: © 2022 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.

PY - 2022/9/26

Y1 - 2022/9/26

N2 - Carboranes are a class of carbon-boron molecular clusters, possessing extraordinary characteristics including three-dimensional aromaticity conjugated by σ-bonds, icosahedral geometry and inherent robustness. They are finding a variety of applications in medicine, materials and coordination/organometallic chemistry, and more. Thus, selective functionalization of o-carboranes has attracted enormous research interests, particularly in regio- and enantio-selective cage BH derivatization among ten chemically similar BH vertices in o-carboranes. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization. This review summarizes recent advances in this research realm.

AB - Carboranes are a class of carbon-boron molecular clusters, possessing extraordinary characteristics including three-dimensional aromaticity conjugated by σ-bonds, icosahedral geometry and inherent robustness. They are finding a variety of applications in medicine, materials and coordination/organometallic chemistry, and more. Thus, selective functionalization of o-carboranes has attracted enormous research interests, particularly in regio- and enantio-selective cage BH derivatization among ten chemically similar BH vertices in o-carboranes. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization. This review summarizes recent advances in this research realm.

KW - Asymmetric catalysis

KW - B-H functionalization

KW - Base-metal catalysis

KW - Boron

KW - Carborane

KW - Cascade reaction

KW - Electrochemistry

KW - Transition-metal catalysis

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SN - 9780323988315

T3 - Advances in Catalysis

SP - 91

EP - 167

BT - Advances in the Synthesis and Catalytic Applications of Boron Clusters

A2 - Diéguez, Montserrat

A2 - Núñez, Rosario

PB - Academic Press Inc.

ER -

Zhang J, Xie Z. Advances in transition metal catalyzed selective B–H functionalization of o-carboranes. In Diéguez M, Núñez R, editors, Advances in the Synthesis and Catalytic Applications of Boron Clusters: A Tribute to the Works of Professor Francesc Teixidor and Professor Clara Viñas. Academic Press Inc. 2022. p. 91-167. (Advances in Catalysis). Epub 2022 May 24. doi: 10.1016/bs.acat.2022.04.003

Advances in transition metal catalyzed selective B–H functionalization of o-carboranes

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