A stable metal cluster-metalloporphyrin MOF with high capacity for cationic dye removal

Zheng Wang; Jian Hua Zhang; Ji Jun Jiang; Hai Ping Wang; Zhang Wen Wei; Xunjin ZHU; Mei Pan; Cheng Yong Su

doi:10.1039/c8ta06249h

A stable metal cluster-metalloporphyrin MOF with high capacity for cationic dye removal

Zheng Wang
, Jian Hua Zhang
, Ji Jun Jiang
, Hai Ping Wang
, Zhang Wen Wei
, Xunjin ZHU^*
, Mei Pan
, Cheng Yong Su

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

133 Citations (Scopus)

Abstract

A metalloporphyrin Cu₅-cluster based MOF (metal-organic framework), [Cu_4.5((H₄TZPP)(TZPP)Cl₂)(H₂O)_0.5]·CH₃NH₂CH₃·7EtOH·8H₂O (LIFM-WZ-3) was synthesized from the tetrapodal ligand 5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrin (H₆TZPP) and copper chloride. LIFM-WZ-3 exhibits a rare 2D + 3D → 3D interpenetration topology, of which the frl-type 3D MOF and a layered 2D HOF (hydrogen bond organic framework) are intertwined, leading to an anionic framework with 1D spindle-like channels. Powder X-ray diffraction analysis reveals that the framework is stable in acid, base and various organic solvent environments. LIFM-WZ-3 exhibits moderately high separation performances for CO₂/CH₄, CO₂/N₂, C₃H₆/CH₄, C₂H₆/CH₄, and C₂H₄/CH₄ at room temperature. Specifically, the anionic framework in LIFM-WZ-3 containing dimethylamine cations can selectively adsorb cationic organic dyes from aqueous pollutants for recycle purpose. The high adsorption capacity for methylene-blue (MB⁺, 983 mg g^-1) and crystal violet (CV⁺, 713.5 mg g^-1) ranks the highest among those MOFs ever reported.

Original language	English
Pages (from-to)	17698-17705
Number of pages	8
Journal	Journal of Materials Chemistry A
Volume	6
Issue number	36
Early online date	21 Aug 2018
DOIs	https://doi.org/10.1039/c8ta06249h
Publication status	Published - 28 Sept 2018

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10.1039/c8ta06249h

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@article{590c1d95a80145d28c22262c76063ae5,

title = "A stable metal cluster-metalloporphyrin MOF with high capacity for cationic dye removal",

abstract = "A metalloporphyrin Cu5-cluster based MOF (metal-organic framework), [Cu4.5((H4TZPP)(TZPP)Cl2)(H2O)0.5]·CH3NH2CH3·7EtOH·8H2O (LIFM-WZ-3) was synthesized from the tetrapodal ligand 5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrin (H6TZPP) and copper chloride. LIFM-WZ-3 exhibits a rare 2D + 3D → 3D interpenetration topology, of which the frl-type 3D MOF and a layered 2D HOF (hydrogen bond organic framework) are intertwined, leading to an anionic framework with 1D spindle-like channels. Powder X-ray diffraction analysis reveals that the framework is stable in acid, base and various organic solvent environments. LIFM-WZ-3 exhibits moderately high separation performances for CO2/CH4, CO2/N2, C3H6/CH4, C2H6/CH4, and C2H4/CH4 at room temperature. Specifically, the anionic framework in LIFM-WZ-3 containing dimethylamine cations can selectively adsorb cationic organic dyes from aqueous pollutants for recycle purpose. The high adsorption capacity for methylene-blue (MB+, 983 mg g-1) and crystal violet (CV+, 713.5 mg g-1) ranks the highest among those MOFs ever reported.",

author = "Zheng Wang and Zhang, \{Jian Hua\} and Jiang, \{Ji Jun\} and Wang, \{Hai Ping\} and Wei, \{Zhang Wen\} and Xunjin ZHU and Mei Pan and Su, \{Cheng Yong\}",

note = "Funding Information: This work was supported by NSFC (21771197, 21720102007), STP Project of Guangzhou (201504010031), NSF of Guangdong Province (S2013030013474), Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01C161), and FRF for the Central Universities. Zhu thanks Hong Kong Research Grants Council (HKBU 22304115-ECS), Areas of Excellence Scheme ([AoE/P-03/08]) for support.",

year = "2018",

month = sep,

day = "28",

doi = "10.1039/c8ta06249h",

language = "English",

volume = "6",

pages = "17698--17705",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

number = "36",

}

TY - JOUR

T1 - A stable metal cluster-metalloporphyrin MOF with high capacity for cationic dye removal

AU - Wang, Zheng

AU - Zhang, Jian Hua

AU - Jiang, Ji Jun

AU - Wang, Hai Ping

AU - Wei, Zhang Wen

AU - ZHU, Xunjin

AU - Pan, Mei

AU - Su, Cheng Yong

N1 - Funding Information: This work was supported by NSFC (21771197, 21720102007), STP Project of Guangzhou (201504010031), NSF of Guangdong Province (S2013030013474), Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01C161), and FRF for the Central Universities. Zhu thanks Hong Kong Research Grants Council (HKBU 22304115-ECS), Areas of Excellence Scheme ([AoE/P-03/08]) for support.

PY - 2018/9/28

Y1 - 2018/9/28

N2 - A metalloporphyrin Cu5-cluster based MOF (metal-organic framework), [Cu4.5((H4TZPP)(TZPP)Cl2)(H2O)0.5]·CH3NH2CH3·7EtOH·8H2O (LIFM-WZ-3) was synthesized from the tetrapodal ligand 5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrin (H6TZPP) and copper chloride. LIFM-WZ-3 exhibits a rare 2D + 3D → 3D interpenetration topology, of which the frl-type 3D MOF and a layered 2D HOF (hydrogen bond organic framework) are intertwined, leading to an anionic framework with 1D spindle-like channels. Powder X-ray diffraction analysis reveals that the framework is stable in acid, base and various organic solvent environments. LIFM-WZ-3 exhibits moderately high separation performances for CO2/CH4, CO2/N2, C3H6/CH4, C2H6/CH4, and C2H4/CH4 at room temperature. Specifically, the anionic framework in LIFM-WZ-3 containing dimethylamine cations can selectively adsorb cationic organic dyes from aqueous pollutants for recycle purpose. The high adsorption capacity for methylene-blue (MB+, 983 mg g-1) and crystal violet (CV+, 713.5 mg g-1) ranks the highest among those MOFs ever reported.

AB - A metalloporphyrin Cu5-cluster based MOF (metal-organic framework), [Cu4.5((H4TZPP)(TZPP)Cl2)(H2O)0.5]·CH3NH2CH3·7EtOH·8H2O (LIFM-WZ-3) was synthesized from the tetrapodal ligand 5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrin (H6TZPP) and copper chloride. LIFM-WZ-3 exhibits a rare 2D + 3D → 3D interpenetration topology, of which the frl-type 3D MOF and a layered 2D HOF (hydrogen bond organic framework) are intertwined, leading to an anionic framework with 1D spindle-like channels. Powder X-ray diffraction analysis reveals that the framework is stable in acid, base and various organic solvent environments. LIFM-WZ-3 exhibits moderately high separation performances for CO2/CH4, CO2/N2, C3H6/CH4, C2H6/CH4, and C2H4/CH4 at room temperature. Specifically, the anionic framework in LIFM-WZ-3 containing dimethylamine cations can selectively adsorb cationic organic dyes from aqueous pollutants for recycle purpose. The high adsorption capacity for methylene-blue (MB+, 983 mg g-1) and crystal violet (CV+, 713.5 mg g-1) ranks the highest among those MOFs ever reported.

UR - https://www.scopus.com/pages/publications/85053658941

U2 - 10.1039/c8ta06249h

DO - 10.1039/c8ta06249h

M3 - Journal article

AN - SCOPUS:85053658941

SN - 2050-7488

VL - 6

SP - 17698

EP - 17705

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 36

ER -

A stable metal cluster-metalloporphyrin MOF with high capacity for cationic dye removal

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