A selectively rhodamine-based colorimetric probe for detecting copper(II) ion

Jiangang Zhang, Li Zhang, Yanli Wei, Jianbing Chao, Shaomin Shuang, Zongwei CAI, Chuan Dong*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

A novel rhodamine derivative 3-bromo-5-methylsalicylaldehyde rhodamine B hydrazone (BMSRH) has been synthesized by reacting rhodamine B hydrazide with 3-bromo-5-methylsalicylaldehyde and developed as a new colorimetric probe for the selective and sensitive detection of Cu2+. Addition of Cu 2+ to the solution of BMSRH results in a rapid color change from colorless to red together with an obvious new band appeared at 552 nm in the UV-vis absorption spectra. This change is attributed to the spirocycle form of BMSRH opened via coordination with Cu2+ in a 1:1 stoichiometry and their association constant is determined as 3.2 × 104 L mol-1. Experimental results indicate that the BMSRH can provide a rapid, selective and sensitive response to Cu2+ with a linear dynamic range 0.667-240 μmol/L. Common interferent ions do not show any interference on the Cu2+ determination. It is anticipated that BMSRH can be a good candidate probe and has potential application for Cu2+ determination. The proposed probe exhibits the following advantages: a quick, simple and facile synthesis.

Original languageEnglish
Pages (from-to)191-197
Number of pages7
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume132
DOIs
Publication statusPublished - 11 Nov 2014

Scopus Subject Areas

  • Analytical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Instrumentation
  • Spectroscopy

User-Defined Keywords

  • 3-bromo-5-methylsalicylaldehyde
  • Colorimetric
  • Copper
  • Hydrazine
  • Probe
  • Rhodamine

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