A rotaxane of a 1,1'-disubstituted ferrocene and β-cyclodextrin

Philip J. Skinner; Stephanie Blair; Ritu Kataky; David Parker

doi:10.1039/b000438n

A rotaxane of a 1,1'-disubstituted ferrocene and β-cyclodextrin

Philip J. Skinner, Stephanie Blair, Ritu Kataky, David Parker^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

30 Citations (Scopus)

Abstract

The synthesis is reported of the first rotaxane involving a bound ferrocenyl moiety and β-cyclodextrin; cyclodextrin groups are used as stoppers; intermediate 1:1 adduct formation in d₈-THF was monitored by HR- DOSY methods (K_d = 25 mM, 293 K) and the product rotaxane, isolated in 11% yield, has been characterised by NMR, CD and MALDI-TOF MS.

Original language	English
Pages (from-to)	265-268
Number of pages	4
Journal	New Journal of Chemistry
Volume	24
Issue number	5
DOIs	https://doi.org/10.1039/b000438n
Publication status	Published - 12 Apr 2000

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title = "A rotaxane of a 1,1'-disubstituted ferrocene and β-cyclodextrin",

abstract = "The synthesis is reported of the first rotaxane involving a bound ferrocenyl moiety and β-cyclodextrin; cyclodextrin groups are used as stoppers; intermediate 1:1 adduct formation in d8-THF was monitored by HR- DOSY methods (Kd = 25 mM, 293 K) and the product rotaxane, isolated in 11% yield, has been characterised by NMR, CD and MALDI-TOF MS.",

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AU - Skinner, Philip J.

AU - Blair, Stephanie

AU - Kataky, Ritu

AU - Parker, David

PY - 2000/4/12

Y1 - 2000/4/12

N2 - The synthesis is reported of the first rotaxane involving a bound ferrocenyl moiety and β-cyclodextrin; cyclodextrin groups are used as stoppers; intermediate 1:1 adduct formation in d8-THF was monitored by HR- DOSY methods (Kd = 25 mM, 293 K) and the product rotaxane, isolated in 11% yield, has been characterised by NMR, CD and MALDI-TOF MS.

AB - The synthesis is reported of the first rotaxane involving a bound ferrocenyl moiety and β-cyclodextrin; cyclodextrin groups are used as stoppers; intermediate 1:1 adduct formation in d8-THF was monitored by HR- DOSY methods (Kd = 25 mM, 293 K) and the product rotaxane, isolated in 11% yield, has been characterised by NMR, CD and MALDI-TOF MS.

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A rotaxane of a 1,1'-disubstituted ferrocene and β-cyclodextrin

Abstract

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