A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

Jing Xiang; Wai Lun Man; Junfang Guo; Shek Man Yiu; Gene Hsiang Lee; Shie Ming Peng; Guancheng Xu; Song Gao; Tai Chu Lau

doi:10.1039/c001732a

A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

Jing Xiang
, Wai Lun Man
, Junfang Guo
, Shek Man Yiu
, Gene Hsiang Lee
, Shie Ming Peng
, Guancheng Xu
, Song Gao^*
, Tai Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

27 Citations (Scopus)

Abstract

Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-Ru^III magnetic materials.

Original language	English
Pages (from-to)	6102-6104
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	33
Early online date	26 Jul 2010
DOIs	https://doi.org/10.1039/c001732a
Publication status	Published - 7 Sept 2010

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10.1039/c001732a

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@article{cf17a845951b478085b28baa3ce22c89,

title = "A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers",

abstract = "Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials.",

author = "Jing Xiang and Man, \{Wai Lun\} and Junfang Guo and Yiu, \{Shek Man\} and Lee, \{Gene Hsiang\} and Peng, \{Shie Ming\} and Guancheng Xu and Song Gao and Lau, \{Tai Chu\}",

note = "The work described in this paper was supported by the Research Grants Council of Hong Kong (N\_CityU 107/08 and CityU 101506), and the National Natural Science Foundation of China (NSFC 20831160505).",

year = "2010",

month = sep,

day = "7",

doi = "10.1039/c001732a",

language = "English",

volume = "46",

pages = "6102--6104",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

AU - Xiang, Jing

AU - Man, Wai Lun

AU - Guo, Junfang

AU - Yiu, Shek Man

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Xu, Guancheng

AU - Gao, Song

AU - Lau, Tai Chu

N1 - The work described in this paper was supported by the Research Grants Council of Hong Kong (N_CityU 107/08 and CityU 101506), and the National Natural Science Foundation of China (NSFC 20831160505).

PY - 2010/9/7

Y1 - 2010/9/7

N2 - Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials.

AB - Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials.

UR - https://www.scopus.com/pages/publications/77955838709

U2 - 10.1039/c001732a

DO - 10.1039/c001732a

M3 - Journal article

AN - SCOPUS:77955838709

SN - 1359-7345

VL - 46

SP - 6102

EP - 6104

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

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