A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

Jing Xiang; Wai Lun Man; Junfang Guo; Shek Man Yiu; Gene Hsiang Lee; Shie Ming Peng; Guancheng Xu; Song Gao; Tai Chu Lau

doi:10.1039/c001732a

A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

Jing Xiang, Wai Lun Man, Junfang Guo, Shek Man Yiu, Gene Hsiang Lee, Shie Ming Peng, Guancheng Xu, Song Gao^*, Tai Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

27 Citations (Scopus)

Abstract

Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-Ru^III magnetic materials.

Original language	English
Pages (from-to)	6102-6104
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	33
Early online date	26 Jul 2010
DOIs	https://doi.org/10.1039/c001732a
Publication status	Published - 7 Sept 2010

Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c001732a

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@article{cf17a845951b478085b28baa3ce22c89,

title = "A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers",

abstract = "Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials.",

author = "Jing Xiang and Man, {Wai Lun} and Junfang Guo and Yiu, {Shek Man} and Lee, {Gene Hsiang} and Peng, {Shie Ming} and Guancheng Xu and Song Gao and Lau, {Tai Chu}",

note = "The work described in this paper was supported by the Research Grants Council of Hong Kong (N_CityU 107/08 and CityU 101506), and the National Natural Science Foundation of China (NSFC 20831160505).",

year = "2010",

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doi = "10.1039/c001732a",

language = "English",

volume = "46",

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T1 - A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

AU - Xiang, Jing

AU - Man, Wai Lun

AU - Guo, Junfang

AU - Yiu, Shek Man

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Xu, Guancheng

AU - Gao, Song

AU - Lau, Tai Chu

N1 - The work described in this paper was supported by the Research Grants Council of Hong Kong (N_CityU 107/08 and CityU 101506), and the National Natural Science Foundation of China (NSFC 20831160505).

PY - 2010/9/7

Y1 - 2010/9/7

N2 - Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials.

AB - Reaction of excess cyanide with a ruthenium(vi) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(iii) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials.

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U2 - 10.1039/c001732a

DO - 10.1039/c001732a

M3 - Journal article

AN - SCOPUS:77955838709

SN - 1359-7345

VL - 46

SP - 6102

EP - 6104

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

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