A novel molecular luminescent sensor for metal ions using deprotonated tetramethylpropane-1,1,3,3-tetracarboxylate as ionophore

Derek Y.K. Lee; Michael H.W. Lam; Wai Yeung WONG

doi:10.1039/b108087n

A novel molecular luminescent sensor for metal ions using deprotonated tetramethylpropane-1,1,3,3-tetracarboxylate as ionophore

Derek Y.K. Lee, Michael H.W. Lam^*, Wai Yeung WONG

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

6 Citations (Scopus)

Abstract

Luminescent properties of the supramolecular complex, [Re(bpy)(CO)₃{py-CH[CH(COOMe)₂]₂}] ⁺ (3, bpy = 2,2′-bipyridine), containing a novel ionophore precursor, py-CH[CH(COOMe)₂]₂ (1), with two adjacent dimethyl malonate moieties joined together by a pyridine substituted methylene bridge, are found to respond selectively to Ba²⁺ upon deprotonation of the two malonate moieties.

Original language	English
Pages (from-to)	330-335
Number of pages	6
Journal	New Journal of Chemistry
Volume	26
Issue number	3
DOIs	https://doi.org/10.1039/b108087n
Publication status	Published - 2002

Scopus Subject Areas

Catalysis
General Chemistry
Materials Chemistry

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title = "A novel molecular luminescent sensor for metal ions using deprotonated tetramethylpropane-1,1,3,3-tetracarboxylate as ionophore",

abstract = "Luminescent properties of the supramolecular complex, [Re(bpy)(CO)3{py-CH[CH(COOMe)2]2}] + (3, bpy = 2,2′-bipyridine), containing a novel ionophore precursor, py-CH[CH(COOMe)2]2 (1), with two adjacent dimethyl malonate moieties joined together by a pyridine substituted methylene bridge, are found to respond selectively to Ba2+ upon deprotonation of the two malonate moieties.",

author = "Lee, {Derek Y.K.} and Lam, {Michael H.W.} and WONG, {Wai Yeung}",

year = "2002",

doi = "10.1039/b108087n",

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journal = "New Journal of Chemistry",

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publisher = "Royal Society of Chemistry",

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AU - Lee, Derek Y.K.

AU - Lam, Michael H.W.

AU - WONG, Wai Yeung

PY - 2002

Y1 - 2002

N2 - Luminescent properties of the supramolecular complex, [Re(bpy)(CO)3{py-CH[CH(COOMe)2]2}] + (3, bpy = 2,2′-bipyridine), containing a novel ionophore precursor, py-CH[CH(COOMe)2]2 (1), with two adjacent dimethyl malonate moieties joined together by a pyridine substituted methylene bridge, are found to respond selectively to Ba2+ upon deprotonation of the two malonate moieties.

AB - Luminescent properties of the supramolecular complex, [Re(bpy)(CO)3{py-CH[CH(COOMe)2]2}] + (3, bpy = 2,2′-bipyridine), containing a novel ionophore precursor, py-CH[CH(COOMe)2]2 (1), with two adjacent dimethyl malonate moieties joined together by a pyridine substituted methylene bridge, are found to respond selectively to Ba2+ upon deprotonation of the two malonate moieties.

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U2 - 10.1039/b108087n

DO - 10.1039/b108087n

M3 - Journal article

AN - SCOPUS:0036204357

SN - 1144-0546

VL - 26

SP - 330

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JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 3

ER -

A novel molecular luminescent sensor for metal ions using deprotonated tetramethylpropane-1,1,3,3-tetracarboxylate as ionophore

Abstract

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