A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions: {[Ni(cyclen)] [Ag(CN)2]} [Ag(CN)2]

I. P.Y. Shek; Wai Yeung Wong; T. C. Lau

doi:10.1039/b004939p

A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions: {[Ni(cyclen)] [Ag(CN)₂]} [Ag(CN)₂]

I. P.Y. Shek, Wai Yeung Wong, T. C. Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

24 Citations (Scopus)

Abstract

Reaction of nickel(II) acetate with cyclen (cyelen = 1,4,7,10-tetraazacyclododecane) and K[Ag(CN)₂] gave {[Ni(cyclen)]-[Ag(CN)₂]} [Ag(CN)₂], which consists of cis-[Ni(cyclen)]²⁺ units bridged by [Ag(CN)₂]^- to form a zig-zag chain; the Ag atoms of the free and bridging [Ag(CN)₂]^- also align together to form an infinite zig-zag chain with short Ag···Ag distances.

Original language	English
Pages (from-to)	733-734
Number of pages	2
Journal	New Journal of Chemistry
Volume	24
Issue number	10
DOIs	https://doi.org/10.1039/b004939p
Publication status	Published - 2000

Scopus Subject Areas

Catalysis
General Chemistry
Materials Chemistry

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title = "A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions: {[Ni(cyclen)] [Ag(CN)2]} [Ag(CN)2]",

abstract = "Reaction of nickel(II) acetate with cyclen (cyelen = 1,4,7,10-tetraazacyclododecane) and K[Ag(CN)2] gave {[Ni(cyclen)]-[Ag(CN)2]} [Ag(CN)2], which consists of cis-[Ni(cyclen)]2+ units bridged by [Ag(CN)2]- to form a zig-zag chain; the Ag atoms of the free and bridging [Ag(CN)2]- also align together to form an infinite zig-zag chain with short Ag···Ag distances.",

author = "Shek, {I. P.Y.} and Wong, {Wai Yeung} and Lau, {T. C.}",

year = "2000",

doi = "10.1039/b004939p",

language = "English",

volume = "24",

pages = "733--734",

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issn = "1144-0546",

publisher = "Royal Society of Chemistry",

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T1 - A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions

T2 - {[Ni(cyclen)] [Ag(CN)2]} [Ag(CN)2]

AU - Shek, I. P.Y.

AU - Wong, Wai Yeung

AU - Lau, T. C.

PY - 2000

Y1 - 2000

N2 - Reaction of nickel(II) acetate with cyclen (cyelen = 1,4,7,10-tetraazacyclododecane) and K[Ag(CN)2] gave {[Ni(cyclen)]-[Ag(CN)2]} [Ag(CN)2], which consists of cis-[Ni(cyclen)]2+ units bridged by [Ag(CN)2]- to form a zig-zag chain; the Ag atoms of the free and bridging [Ag(CN)2]- also align together to form an infinite zig-zag chain with short Ag···Ag distances.

AB - Reaction of nickel(II) acetate with cyclen (cyelen = 1,4,7,10-tetraazacyclododecane) and K[Ag(CN)2] gave {[Ni(cyclen)]-[Ag(CN)2]} [Ag(CN)2], which consists of cis-[Ni(cyclen)]2+ units bridged by [Ag(CN)2]- to form a zig-zag chain; the Ag atoms of the free and bridging [Ag(CN)2]- also align together to form an infinite zig-zag chain with short Ag···Ag distances.

UR - http://www.scopus.com/inward/record.url?scp=0033774988&partnerID=8YFLogxK

U2 - 10.1039/b004939p

DO - 10.1039/b004939p

M3 - Journal article

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SN - 1144-0546

VL - 24

SP - 733

EP - 734

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 10

ER -

A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions: {[Ni(cyclen)] [Ag(CN)₂]} [Ag(CN)₂]

Abstract

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