A novel Cd complex with 3D framework containing perpendicular chains and helices

Hong Mei Shen; Jian Zhang; Pei Xiu Yin; Zhao Ji Li; Zongwei CAI; Yuan Gen Yao

doi:10.1016/j.molstruc.2006.04.044

A novel Cd complex with 3D framework containing perpendicular chains and helices

Hong Mei Shen
, Jian Zhang
, Pei Xiu Yin
, Zhao Ji Li
, Zongwei CAI
, Yuan Gen Yao^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

3 Citations (Scopus)

Abstract

The hydrothermal reaction of CdBr₂ · 2H₂O with a flexible multicarboxylate ligand, trans-aconitic acid (H₃L), produced a novel coordination compound [Cd₃L₂(H₂O)₆]_n. It crystallizes in the space group C2/c with a = 17.1304(1) Å, b = 9.5611(2) Å, c = 14.0137(2) Å, β = 115.96°, Z = 4, V = 2063.65(5) Å³. The unique feature of the structure is an unprecedented 3D framework containing infinite Cd(1)-O-C linear chains and heterochiral Cd(2)-O-C single-stranded helices. These linear chains and helices happen to be perpendicular to each other.

Original language	English
Pages (from-to)	126-130
Number of pages	5
Journal	Journal of Molecular Structure
Volume	826
Issue number	2-3
DOIs	https://doi.org/10.1016/j.molstruc.2006.04.044
Publication status	Published - 29 Jan 2007

User-Defined Keywords

3D framework
Perpendicular
Single-stranded helix
trans-Aconitic acid

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10.1016/j.molstruc.2006.04.044

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@article{dc6aedd29b1548f291c13e5e0081e677,

title = "A novel Cd complex with 3D framework containing perpendicular chains and helices",

abstract = "The hydrothermal reaction of CdBr2 · 2H2O with a flexible multicarboxylate ligand, trans-aconitic acid (H3L), produced a novel coordination compound [Cd3L2(H2O)6]n. It crystallizes in the space group C2/c with a = 17.1304(1) {\AA}, b = 9.5611(2) {\AA}, c = 14.0137(2) {\AA}, β = 115.96°, Z = 4, V = 2063.65(5) {\AA}3. The unique feature of the structure is an unprecedented 3D framework containing infinite Cd(1)-O-C linear chains and heterochiral Cd(2)-O-C single-stranded helices. These linear chains and helices happen to be perpendicular to each other.",

keywords = "3D framework, Perpendicular, Single-stranded helix, trans-Aconitic acid",

author = "Shen, \{Hong Mei\} and Jian Zhang and Yin, \{Pei Xiu\} and Li, \{Zhao Ji\} and Zongwei CAI and Yao, \{Yuan Gen\}",

note = "Funding Information: This work is supported by the National Natural Science Foundation of China under project No. 20173063, YIF of Fujian Province (2005J060), the Major Special Foundation of Fujian Province (2005H201-1) and the NSF of Fujian Province (E0020001).",

year = "2007",

month = jan,

day = "29",

doi = "10.1016/j.molstruc.2006.04.044",

language = "English",

volume = "826",

pages = "126--130",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "2-3",

}

TY - JOUR

T1 - A novel Cd complex with 3D framework containing perpendicular chains and helices

AU - Shen, Hong Mei

AU - Zhang, Jian

AU - Yin, Pei Xiu

AU - Li, Zhao Ji

AU - CAI, Zongwei

AU - Yao, Yuan Gen

N1 - Funding Information: This work is supported by the National Natural Science Foundation of China under project No. 20173063, YIF of Fujian Province (2005J060), the Major Special Foundation of Fujian Province (2005H201-1) and the NSF of Fujian Province (E0020001).

PY - 2007/1/29

Y1 - 2007/1/29

N2 - The hydrothermal reaction of CdBr2 · 2H2O with a flexible multicarboxylate ligand, trans-aconitic acid (H3L), produced a novel coordination compound [Cd3L2(H2O)6]n. It crystallizes in the space group C2/c with a = 17.1304(1) Å, b = 9.5611(2) Å, c = 14.0137(2) Å, β = 115.96°, Z = 4, V = 2063.65(5) Å3. The unique feature of the structure is an unprecedented 3D framework containing infinite Cd(1)-O-C linear chains and heterochiral Cd(2)-O-C single-stranded helices. These linear chains and helices happen to be perpendicular to each other.

AB - The hydrothermal reaction of CdBr2 · 2H2O with a flexible multicarboxylate ligand, trans-aconitic acid (H3L), produced a novel coordination compound [Cd3L2(H2O)6]n. It crystallizes in the space group C2/c with a = 17.1304(1) Å, b = 9.5611(2) Å, c = 14.0137(2) Å, β = 115.96°, Z = 4, V = 2063.65(5) Å3. The unique feature of the structure is an unprecedented 3D framework containing infinite Cd(1)-O-C linear chains and heterochiral Cd(2)-O-C single-stranded helices. These linear chains and helices happen to be perpendicular to each other.

KW - 3D framework

KW - Perpendicular

KW - Single-stranded helix

KW - trans-Aconitic acid

UR - https://www.scopus.com/pages/publications/33846016262

U2 - 10.1016/j.molstruc.2006.04.044

DO - 10.1016/j.molstruc.2006.04.044

M3 - Journal article

AN - SCOPUS:33846016262

SN - 0022-2860

VL - 826

SP - 126

EP - 130

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 2-3

ER -

A novel Cd complex with 3D framework containing perpendicular chains and helices

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