A glucose selective electrode based on calix[6]arene and application in human serum assay

Wing Hong Chan; Yee Ling Wong-Leung; Tse Fai Lai; Ruo Yuan

doi:10.1080/00032719708002289

A glucose selective electrode based on calix[6]arene and application in human serum assay

Wing Hong Chan^*, Yee Ling Wong-Leung, Tse Fai Lai, Ruo Yuan

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

4 Citations (Scopus)

Abstract

Plasticized ploy(vinyl chloride) (PVC) membranes incorporating dealkylcalix[6]arene as a sensory material were developed for the determination of glucose after its in situ derivatization with a lipophilic Girard's P' reagent. In a TRIS-HCl buffer at pH 9.0, the electrode exhibits a near Nernstian response in the range 1.0 x 10^-4 - 0.01 mol 1^-1 glucose with a slope of 45.5 mV per concentration decade. The electrode has a fast response time and a long working lifetime. The selectivity of this electrode method allow its application to the assay of glucose concentration in human blood samples.

Original language	English
Pages (from-to)	45-59
Number of pages	15
Journal	Analytical Letters
Volume	30
Issue number	1
DOIs	https://doi.org/10.1080/00032719708002289
Publication status	Published - 1997

Scopus Subject Areas

Analytical Chemistry
Biochemistry
Spectroscopy
Clinical Biochemistry
Biochemistry, medical
Electrochemistry

User-Defined Keywords

Calixarene
Girard's type reagents
Glucose determination
Host-guest interaction
Ion-selective electrode

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10.1080/00032719708002289

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title = "A glucose selective electrode based on calix[6]arene and application in human serum assay",

abstract = "Plasticized ploy(vinyl chloride) (PVC) membranes incorporating dealkylcalix[6]arene as a sensory material were developed for the determination of glucose after its in situ derivatization with a lipophilic Girard's P' reagent. In a TRIS-HCl buffer at pH 9.0, the electrode exhibits a near Nernstian response in the range 1.0 x 10-4 - 0.01 mol 1-1 glucose with a slope of 45.5 mV per concentration decade. The electrode has a fast response time and a long working lifetime. The selectivity of this electrode method allow its application to the assay of glucose concentration in human blood samples.",

keywords = "Calixarene, Girard's type reagents, Glucose determination, Host-guest interaction, Ion-selective electrode",

author = "Chan, {Wing Hong} and Wong-Leung, {Yee Ling} and Lai, {Tse Fai} and Ruo Yuan",

year = "1997",

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language = "English",

volume = "30",

pages = "45--59",

journal = "Analytical Letters",

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TY - JOUR

T1 - A glucose selective electrode based on calix[6]arene and application in human serum assay

AU - Chan, Wing Hong

AU - Wong-Leung, Yee Ling

AU - Lai, Tse Fai

AU - Yuan, Ruo

PY - 1997

Y1 - 1997

N2 - Plasticized ploy(vinyl chloride) (PVC) membranes incorporating dealkylcalix[6]arene as a sensory material were developed for the determination of glucose after its in situ derivatization with a lipophilic Girard's P' reagent. In a TRIS-HCl buffer at pH 9.0, the electrode exhibits a near Nernstian response in the range 1.0 x 10-4 - 0.01 mol 1-1 glucose with a slope of 45.5 mV per concentration decade. The electrode has a fast response time and a long working lifetime. The selectivity of this electrode method allow its application to the assay of glucose concentration in human blood samples.

AB - Plasticized ploy(vinyl chloride) (PVC) membranes incorporating dealkylcalix[6]arene as a sensory material were developed for the determination of glucose after its in situ derivatization with a lipophilic Girard's P' reagent. In a TRIS-HCl buffer at pH 9.0, the electrode exhibits a near Nernstian response in the range 1.0 x 10-4 - 0.01 mol 1-1 glucose with a slope of 45.5 mV per concentration decade. The electrode has a fast response time and a long working lifetime. The selectivity of this electrode method allow its application to the assay of glucose concentration in human blood samples.

KW - Calixarene

KW - Girard's type reagents

KW - Glucose determination

KW - Host-guest interaction

KW - Ion-selective electrode

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U2 - 10.1080/00032719708002289

DO - 10.1080/00032719708002289

M3 - Journal article

AN - SCOPUS:0343118143

SN - 0003-2719

VL - 30

SP - 45

EP - 59

JO - Analytical Letters

JF - Analytical Letters

IS - 1

ER -

A glucose selective electrode based on calix[6]arene and application in human serum assay

Abstract

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