A dinuclear rhodium-carbonyl cryptate of a ditopic macrocyclic ligand

Jean Pierre Lecomte; Jean Marie Lehn; David Parker; Jean Guilhem; Claudine Pascard

doi:10.1039/C39830000296

A dinuclear rhodium-carbonyl cryptate of a ditopic macrocyclic ligand

Jean Pierre Lecomte
, Jean Marie Lehn^*
, David Parker
, Jean Guilhem
, Claudine Pascard

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

26 Citations (Scopus)

Abstract

Reaction of the ditopic hexa-aza-macrocycle (1) with tetracarbonyldichlorodirhodium(I) yields the dinuclear rhodium-carbonyl complex (1)-Rh₂, which may be considered as a cryptate of a triply bridged [Rh(CO)₃Rh]²⁺ unit held inside the intramolecular cavity of the ligand.

Original language	English
Pages (from-to)	296-298
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/C39830000296
Publication status	Published - Mar 1983

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@article{f32df5bd61054326abe027295d54fabd,

title = "A dinuclear rhodium-carbonyl cryptate of a ditopic macrocyclic ligand",

abstract = "Reaction of the ditopic hexa-aza-macrocycle (1) with tetracarbonyldichlorodirhodium(I) yields the dinuclear rhodium-carbonyl complex (1)-Rh2, which may be considered as a cryptate of a triply bridged [Rh(CO)3Rh]2+ unit held inside the intramolecular cavity of the ligand.",

author = "Lecomte, \{Jean Pierre\} and Lehn, \{Jean Marie\} and David Parker and Jean Guilhem and Claudine Pascard",

year = "1983",

month = mar,

doi = "10.1039/C39830000296",

language = "English",

pages = "296--298",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "6",

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TY - JOUR

T1 - A dinuclear rhodium-carbonyl cryptate of a ditopic macrocyclic ligand

AU - Lecomte, Jean Pierre

AU - Lehn, Jean Marie

AU - Parker, David

AU - Guilhem, Jean

AU - Pascard, Claudine

PY - 1983/3

Y1 - 1983/3

N2 - Reaction of the ditopic hexa-aza-macrocycle (1) with tetracarbonyldichlorodirhodium(I) yields the dinuclear rhodium-carbonyl complex (1)-Rh2, which may be considered as a cryptate of a triply bridged [Rh(CO)3Rh]2+ unit held inside the intramolecular cavity of the ligand.

AB - Reaction of the ditopic hexa-aza-macrocycle (1) with tetracarbonyldichlorodirhodium(I) yields the dinuclear rhodium-carbonyl complex (1)-Rh2, which may be considered as a cryptate of a triply bridged [Rh(CO)3Rh]2+ unit held inside the intramolecular cavity of the ligand.

UR - https://www.scopus.com/pages/publications/37049109049

U2 - 10.1039/C39830000296

DO - 10.1039/C39830000296

M3 - Journal article

AN - SCOPUS:37049109049

SN - 0022-4936

SP - 296

EP - 298

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 6

ER -

A dinuclear rhodium-carbonyl cryptate of a ditopic macrocyclic ligand

Abstract

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