A carbide catalyst effective for the dry reforming of methane at atmospheric pressure

Jun Guo; An Jie Zhang; Ai Min Zhu; Yong Xu; C. T. Au; Chuan Shi

doi:10.1021/bk-2010-1056.ch012

A carbide catalyst effective for the dry reforming of methane at atmospheric pressure

Jun Guo, An Jie Zhang, Ai Min Zhu, Yong Xu, C. T. Au, Chuan Shi

Department of Chemistry

Research output: Chapter in book/report/conference proceeding › Conference proceeding › peer-review

12 Citations (Scopus)

Abstract

A catalyst composed of metallic nickel and molybdenum carbide has been fabricated for CO₂ reforming of CH₄. Aspects concerning the formation of Ni and Mo₂C, their synergistic effects for CH ₄ and CO₂ activation, and the establishment of a redox cycle were studied. Due to the catalytic oxidation-recarburization cycle, the Ni-Mo₂C catalyst is superior to the traditional metal carbide catalysts as verified by its stable activity in the dry reforming of CH ₄ at atomspheric pressure.

Original language	English
Title of host publication	Advances in CO2 Conversion and Utilization
Publisher	American Chemical Society
Pages	181-196
Number of pages	16
ISBN (Print)	9780841225961
DOIs	https://doi.org/10.1021/bk-2010-1056.ch012
Publication status	Published - 3 Dec 2010

Publication series

Name	ACS Symposium Series
Volume	1056
ISSN (Print)	0097-6156
ISSN (Electronic)	1947-5918

Scopus Subject Areas

General Chemistry
General Chemical Engineering

Access to Document

10.1021/bk-2010-1056.ch012

Cite this

@inproceedings{c038cc5cea1748d3a9c2d365acc1de5b,

title = "A carbide catalyst effective for the dry reforming of methane at atmospheric pressure",

abstract = "A catalyst composed of metallic nickel and molybdenum carbide has been fabricated for CO2 reforming of CH4. Aspects concerning the formation of Ni and Mo2C, their synergistic effects for CH 4 and CO2 activation, and the establishment of a redox cycle were studied. Due to the catalytic oxidation-recarburization cycle, the Ni-Mo2C catalyst is superior to the traditional metal carbide catalysts as verified by its stable activity in the dry reforming of CH 4 at atomspheric pressure.",

author = "Jun Guo and Zhang, {An Jie} and Zhu, {Ai Min} and Yong Xu and Au, {C. T.} and Chuan Shi",

year = "2010",

month = dec,

day = "3",

doi = "10.1021/bk-2010-1056.ch012",

language = "English",

isbn = "9780841225961",

series = "ACS Symposium Series",

publisher = "American Chemical Society",

pages = "181--196",

booktitle = "Advances in CO2 Conversion and Utilization",

address = "United States",

}

TY - GEN

T1 - A carbide catalyst effective for the dry reforming of methane at atmospheric pressure

AU - Guo, Jun

AU - Zhang, An Jie

AU - Zhu, Ai Min

AU - Xu, Yong

AU - Au, C. T.

AU - Shi, Chuan

PY - 2010/12/3

Y1 - 2010/12/3

N2 - A catalyst composed of metallic nickel and molybdenum carbide has been fabricated for CO2 reforming of CH4. Aspects concerning the formation of Ni and Mo2C, their synergistic effects for CH 4 and CO2 activation, and the establishment of a redox cycle were studied. Due to the catalytic oxidation-recarburization cycle, the Ni-Mo2C catalyst is superior to the traditional metal carbide catalysts as verified by its stable activity in the dry reforming of CH 4 at atomspheric pressure.

AB - A catalyst composed of metallic nickel and molybdenum carbide has been fabricated for CO2 reforming of CH4. Aspects concerning the formation of Ni and Mo2C, their synergistic effects for CH 4 and CO2 activation, and the establishment of a redox cycle were studied. Due to the catalytic oxidation-recarburization cycle, the Ni-Mo2C catalyst is superior to the traditional metal carbide catalysts as verified by its stable activity in the dry reforming of CH 4 at atomspheric pressure.

UR - http://www.scopus.com/inward/record.url?scp=84905510073&partnerID=8YFLogxK

U2 - 10.1021/bk-2010-1056.ch012

DO - 10.1021/bk-2010-1056.ch012

M3 - Conference proceeding

AN - SCOPUS:84905510073

SN - 9780841225961

T3 - ACS Symposium Series

SP - 181

EP - 196

BT - Advances in CO2 Conversion and Utilization

PB - American Chemical Society

ER -

A carbide catalyst effective for the dry reforming of methane at atmospheric pressure

Abstract

Publication series

Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this